Yang Hui, Cai Sa, Zhang Yifei, Wu Dongping, Fang Xiaosheng
Department of Materials Science, Fudan University, Shanghai 200433, P.R. China.
State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433, P.R. China.
J Phys Chem Lett. 2021 Mar 25;12(11):2705-2711. doi: 10.1021/acs.jpclett.1c00231. Epub 2021 Mar 11.
Molybdenum disulfide (MoS) as a two-dimensional semiconductor material has been actively explored for field-effect-transistors (FETs). The current prevailing method for MoS FET fabrication involves multiple complex steps, including electron beam (e-beam) lithography, annealing, ., which are time-consuming and require polymer resists. As a consequence, the MoS exposed to chemicals during the patterning process may be unfavorably affected by residues and the performance of the final FET could be impaired while the annealing limits materials for FETs. Therefore, there is an urgent need to free the fabrication of FETs from e-beam lithography and annealing. In this study, we introduce an e-beam lithography-free method to fabricate MoS FETs by employing maze-like source/drain electrodes. In addition, an ohmic contact in multilayer MoS FETs using chromium (Cr) as source/drain electrodes is achieved without annealing. The underlying mechanism for contact performance is studied, and the tightness of the contact and the type of metal are found to be responsible because they determine the contact resistance. Furthermore, the long-term device degradation is explored, in which the oxidation of metal dominates. The facile fabrication process and mechanism explanation in this work might provide a new platform for future electronic devices.
二硫化钼(MoS)作为一种二维半导体材料,已被积极探索用于场效应晶体管(FET)。当前用于制造MoS FET的主流方法涉及多个复杂步骤,包括电子束(e-beam)光刻、退火等,这些步骤耗时且需要聚合物抗蚀剂。因此,在图案化过程中暴露于化学物质的MoS可能会受到残留物的不利影响,并且最终FET的性能可能会受损,同时退火也限制了FET的材料选择。因此,迫切需要摆脱电子束光刻和退火来制造FET。在本研究中,我们介绍了一种通过采用迷宫状源极/漏极电极来制造MoS FET的无电子束光刻方法。此外,在多层MoS FET中使用铬(Cr)作为源极/漏极电极时,无需退火即可实现欧姆接触。研究了接触性能的潜在机制,发现接触的紧密程度和金属类型是造成这种情况的原因,因为它们决定了接触电阻。此外,还探索了长期器件退化问题,其中金属氧化起主导作用。这项工作中简便的制造工艺和机理解释可能为未来的电子器件提供一个新平台。