Department of Chemistry and Division of Environment, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.
Department of Atmospheric Sciences, National Central University, Taoyuan 32001, Taiwan.
Environ Sci Technol. 2021 Apr 20;55(8):5128-5135. doi: 10.1021/acs.est.0c08327. Epub 2021 Mar 12.
In this study, we assessed the feasibility of using ordinary face masks as a sampling means to collect airborne polycyclic aromatic hydrocarbons (PAHs). Nonwoven fabric masks can trap three-ring or larger PAHs at a high efficiency (>70%) and naphthalene at ∼17%. The sampling method is quantitative as confirmed by comparison with the standard method of the National Institute for Occupational Safety and Health. In conjunction with sensitive fluorescence detection, the method was applied to quantify nine airborne PAHs in a range of indoor and outdoor environments. Wearing the mask for 2 h allowed quantification of individual PAHs as low as 0.07 ng/m. The demonstration shows applicability of the method in monitoring PAHs down to ∼30-80 ng/m in university office and laboratory settings and up to ∼900 ng/m in an incense-burning temple. Compared with traditional filter-/sorbent tube-based approaches, which require a sampling pump, our new method is simple, convenient, and inexpensive. More importantly, it closely tracks human exposure down to the individual level, thus having great potential to facilitate routine occupational exposure monitoring and large-scale surveillance of PAH concentrations in indoor and outdoor environments.
在这项研究中,我们评估了使用普通口罩作为采集空气中多环芳烃(PAHs)的采样手段的可行性。非织造布口罩可以高效(>70%)捕集三环或更大的 PAHs 以及萘(~17%)。采样方法是定量的,这一点通过与美国国家职业安全与健康研究所的标准方法进行比较得到了证实。结合灵敏的荧光检测,该方法被应用于定量分析一系列室内和室外环境中的九种空气中的 PAHs。佩戴口罩 2 小时,可以定量检测到低至 0.07ng/m 的单个 PAHs。该研究结果表明,该方法在监测 PAHs 方面具有适用性,其检测下限可低至大学办公室和实验室环境中的 30-80ng/m,以及香火缭绕的庙宇中的 900ng/m。与传统的基于滤膜/吸附管并需要采样泵的方法相比,我们的新方法简单、方便且经济实惠。更重要的是,它可以密切跟踪个体水平的人体暴露情况,因此在促进常规职业暴露监测和室内外环境中 PAH 浓度的大规模监测方面具有巨大潜力。