Department of Advanced Materials and Engineering, Chosun University, Gwangju 61452, Korea.
J Nanosci Nanotechnol. 2021 Jul 1;21(7):3877-3881. doi: 10.1166/jnn.2021.19203.
Two types of dense and toughened 3Y-TZP zirconia implants were fabricated by the sintering of green compacts. Then, the sintered properties of the two implants were compared. Slip-cast and post-sintered all-ceramic zirconia implants were fabricated by the heat treatment at 1450 °C for 2 h using optimal slurry conditions (60 wt% solid content, 1 wt% dispersant, and pH 12). Computer-aided design and manufacturing (CAD/CAM)-machined and post-sintered zirconia crowns, supplied by a dental hospital, were obtained by sintering at 1650 °C for 5 h. The X-ray diffraction results indicated that the phase composition of the slip-casted specimen was completely tetragonal, but the CAD/CAM machined sample was composed of mixed phases of main tetragonal and minor monoclinic crystals. The sintered density and Vickers hardness of the slip-casted specimen were 6.07 g/cm³ and 1367 Hv, respectively, and these were higher than those of the CAD/CAM machined specimen. From the comparative results of the surface microstructure, hardness, and roughness between the two sintered specimens, the slip-casted specimen was found to have higher surface roughness and mechanical hardness, smaller grain size, and less surface micro-cracks than the CAD/CAM machined specimen.
两种致密增韧 3Y-TZP 氧化锆植入物通过生坯的烧结来制备。然后,比较了两种植入物的烧结性能。采用最佳浆料条件(60wt%固含量、1wt%分散剂和 pH 值 12),通过在 1450°C 下热处理 2 小时,制备了流延和后烧结的全陶瓷氧化锆植入物。通过在 1650°C 下烧结 5 小时,获得了由牙科医院提供的 CAD/CAM 加工和后烧结氧化锆牙冠。X 射线衍射结果表明,流延坯的相组成完全为四方相,但 CAD/CAM 加工的样品由主要四方相和少量单斜相晶体组成。流延坯的烧结密度和维氏硬度分别为 6.07g/cm³和 1367Hv,高于 CAD/CAM 加工样品。从两种烧结样品的表面微观结构、硬度和粗糙度的比较结果来看,流延坯的表面粗糙度和机械硬度较高,晶粒尺寸较小,表面微裂纹较少。