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基于癸酸-石蜡/膨胀石墨的复合相变储能石膏板的制备与性能

Preparation and Properties of a Composite Phase Change Energy Storage Gypsum Board Based on Capric Acid-Paraffin/Expanded Graphite.

作者信息

Fei Hua, Wang Linya, He Qian, Du Wenqing, Gu Qingjun, Pan Yucheng

机构信息

The Laboratory of Architectural Environment and Energy Application Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, China.

出版信息

ACS Omega. 2021 Feb 25;6(9):6144-6152. doi: 10.1021/acsomega.0c05058. eCollection 2021 Mar 9.

Abstract

Energy has become the key material basis of social development. In this work, liquid capric acid-paraffin was evenly adsorbed in the pore structure of expanded graphite (EG) by a physical adsorption method, and the new composite phase change material of capric acid-paraffin/expanded graphite (CA-P/EG) was prepared. The Fourier transform infrared (FT-IR) curves of CA-P/EG composites did not change after 1000 cycles, and there was no new characteristic absorption peak, indicating that CA-P/EG composites have good chemical stability. The results showed that the optimum content of CA-P/EG in a phase change energy storage gypsum board was 20%, and the wet bending strength and compressive strength were 2.42 and 6.45 MPa, respectively. The water absorption was 16.37%, and the apparent density was 1.410 g/cm. In addition, the melting and freezing temperatures were 26.40 and 23.10 °C, and the latent heats of melting and freezing were 27.20 and 25.69 J/g, respectively. It was found that the gypsum board has excellent thermal stability after 400 times of melting-freezing cycling and that the heat storage capacity increases with the increase of the CA-P/EG content and the thickness of the gypsum board.

摘要

能源已成为社会发展的关键物质基础。在本工作中,通过物理吸附法将液态癸酸 - 石蜡均匀吸附在膨胀石墨(EG)的孔隙结构中,制备了新型癸酸 - 石蜡/膨胀石墨复合相变材料(CA - P/EG)。CA - P/EG复合材料的傅里叶变换红外(FT - IR)曲线在1000次循环后未发生变化,且没有新的特征吸收峰,表明CA - P/EG复合材料具有良好的化学稳定性。结果表明,相变储能石膏板中CA - P/EG的最佳含量为20%,其湿弯曲强度和抗压强度分别为2.42 MPa和6.45 MPa。吸水率为16.37%,表观密度为1.410 g/cm³。此外,其熔化温度和凝固温度分别为26.40℃和23.10℃,熔化潜热和凝固潜热分别为27.20 J/g和25.69 J/g。研究发现,经过400次熔化 - 凝固循环后,石膏板具有优异的热稳定性,且储热能力随CA - P/EG含量和石膏板厚度的增加而提高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6579/7948235/9f68a4179324/ao0c05058_0002.jpg

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