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全溶液法制备的氧化钼包覆银纳米线柔性透明导体,具有改善的导电性和附着力。

All-Solution-Processed Molybdenum Oxide-Encapsulated Silver Nanowire Flexible Transparent Conductors with Improved Conductivity and Adhesion.

作者信息

Yu Shihui, Liu Xiaoyu, Wu Muying, Dong Helei, Wang Xiaohu, Li Lingxia

机构信息

School of Microelectronics and Tianjin Key Laboratory of Imaging and Sensing Microelectronic Technology, Tianjin University, Tianjin 300072, P. R. China.

School of Electronic Engineering and Intelligentization, Dongguan University of Technology, Guangdong, Dongguan 523808, China.

出版信息

ACS Appl Mater Interfaces. 2021 Mar 31;13(12):14470-14478. doi: 10.1021/acsami.0c22324. Epub 2021 Mar 18.

Abstract

A novel transparent conductive conductor composed of a silver nanowire (AgNW) network and MoO on a flexible polyethylene terephthalate (PET) substrate, with contemporaneously improved adhesion and reduced resistivity, is prepared using the full-solution process without high-temperature annealing. Under the optimized conditions, a MoO/AgNW/MoO multilayer is achieved, which shows much superior optoelectronic performance to that obtained from ITO with a high optical transmittance of 89.2% and a low sheet resistance of ∼12.5 Ω/sq. Unlike pure AgNW films, the sheet resistance is little changed after the tape and ultrasonication tests, illustrating a very strong adhesion to the PET substrate after the encapsulation of MoO. Moreover, the multilayer film exhibits excellent stability to resist mechanical bending and acid damage. In addition, the successful implementation of the flexible transparent heater demonstrates the practical application value of the electrode.

摘要

一种由银纳米线(AgNW)网络和MoO组成的新型透明导电导体,制备于柔性聚对苯二甲酸乙二醇酯(PET)基板上,通过全溶液工艺制备,无需高温退火,同时实现了附着力的提高和电阻率的降低。在优化条件下,获得了MoO/AgNW/MoO多层结构,其光电性能比ITO优异得多,具有89.2%的高透光率和约12.5Ω/sq的低方块电阻。与纯AgNW薄膜不同,在胶带和超声测试后,方块电阻变化很小,这表明在封装MoO后,其与PET基板具有很强的附着力。此外,多层膜表现出优异的稳定性,能够抵抗机械弯曲和酸损伤。此外,柔性透明加热器的成功实现证明了该电极的实际应用价值。

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