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具有高热稳定性的溶液处理银纳米线/铟锡氧化物纳米颗粒混合透明导体。

Solution-processed silver nanowire/indium-tin-oxide nanoparticle hybrid transparent conductors with high thermal stability.

作者信息

Hong Sung-Jei, Kim Jong-Woong, Kim Yong-Hoon

出版信息

J Nanosci Nanotechnol. 2014 Dec;14(12):9504-9. doi: 10.1166/jnn.2014.10158.

DOI:10.1166/jnn.2014.10158
PMID:25971091
Abstract

In this study, solution-processed hybrid structure transparent conductors consisting of silver nanowires (AgNWs) and indium-tin-oxide nanoparticle (ITO-NP) layers are investigated. Fabricated transparent conductors had stacked structures of ITO-NP/AgNW and ITO-NP/AgNW/ITO-NP, and a successful integration was possible on glass substrates. Compared to a single-layered ITO-NP film which has a sheet resistance value of 1.31 k Ω/⟂, a remarkable enhancement in sheet resistance was achieved from the hybrid structures, showing sheet resistance values of 44.74 Ω/⟂ and 28.07 Ω/⟂ for ITO-NP/AgNW and ITO-NP/AgNW/ITO-NP structures, respectively. In addition, the ITO-NP/AgNW/ITO-NP triple-layered transparent conductor showed greatly enhanced thermal stability in terms of sheet resistance and transmittance against a high-temperature environment up to 300 degrees C. Based on these results, it can be suggested that the hybrid structure has advantages of enhancing both electrical properties of ITO-NP layer and thermal stability of AgNW layer, and we believe the hybrid structure transparent conductors can be a suitable option for applications which require high electrical conductivity, transmittance, and thermal stability.

摘要

在本研究中,对由银纳米线(AgNWs)和氧化铟锡纳米颗粒(ITO-NP)层组成的溶液处理混合结构透明导体进行了研究。制备的透明导体具有ITO-NP/AgNW和ITO-NP/AgNW/ITO-NP的堆叠结构,并且能够成功集成在玻璃基板上。与具有1.31 kΩ/⟂的薄层电阻值的单层ITO-NP薄膜相比,混合结构的薄层电阻有显著提高,ITO-NP/AgNW和ITO-NP/AgNW/ITO-NP结构的薄层电阻值分别为44.74Ω/⟂和28.07Ω/⟂。此外,ITO-NP/AgNW/ITO-NP三层透明导体在高达300摄氏度的高温环境下,在薄层电阻和透射率方面表现出大大增强的热稳定性。基于这些结果,可以认为混合结构具有增强ITO-NP层的电学性能和AgNW层的热稳定性的优点,并且我们相信混合结构透明导体对于需要高电导率、透射率和热稳定性的应用可能是一个合适的选择。

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