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三丁基锡作为一种分子化学试剂-原发性和继发性三丁基锡基镓烷及其较轻同系物的靶向合成。

Stibine as a reagent in molecular chemistry - targeted synthesis of primary and secondary stibanyl-gallanes and their lighter homologues.

机构信息

Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, Marburg 35043, Germany.

出版信息

Chem Commun (Camb). 2021 Apr 21;57(31):3781-3784. doi: 10.1039/d0cc08419k. Epub 2021 Mar 18.

DOI:10.1039/d0cc08419k
PMID:33735342
Abstract

The reactions of SbH with one or two equivalents of (DippNacNac)Ga (DippNacNac = HC{C(Me)N(Dipp)}; Dipp = 2,6-iPrCH) yield the primary and secondary stibanes (DippNacNac)GaH(SbH) (3) and {(DippNacNac)GaH}(SbH) (5). Their lighter homologs were obtained from the analogous reactions with phosphine and arsine. All compounds were characterized using heteronuclear NMR-spectroscopy, IR-spectroscopy and single-crystal X-ray diffraction.

摘要

三氢化锑(SbH)与一当量或两当量的(DippNacNac)Ga（DippNacNac = HC{C(Me)N(Dipp)}; Dipp = 2,6-iPrCH）反应，生成一级和二级的锑烷（DippNacNac）GaH(SbH)（3）和{(DippNacNac)GaH}(SbH)（5）。它们的同系物较轻的化合物是通过与膦和胂类似的反应得到的。所有化合物均采用异核 NMR 光谱、红外光谱和单晶 X 射线衍射进行了表征。

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