Schneider Selina, von Hänisch Carsten
Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, Marburg 35043, Germany.
Chem Commun (Camb). 2022 Feb 1;58(10):1522-1525. doi: 10.1039/d1cc06741a.
(DippNacNac)Ga (DippNacNac = HC{C(Me)N(Dipp)}; Dipp = 2,6-iPrCH) was used as a trapping reagent for the unstable compounds BuSbH and MeBiH to yield (DippNacNac)GaH(SbHBu) (1) and {(DippNacNac)GaH(BiMe)} (2). Moreover, its reactions with a row of alkylated or arylated dichloro-bismuthenes resulted in either bridged species or the formation of a dibismuthane.
（二异丙基萘基）镓（二异丙基萘基 = HC{C(Me)N(二异丙基)}；二异丙基 = 2,6 - 二异丙基苯基）被用作不稳定化合物丁基锑化氢和甲基铋化氢的捕获试剂，以生成（二异丙基萘基）镓氢（锑氢丁基）（1）和{（二异丙基萘基）镓氢（铋甲基）}（2）。此外，它与一系列烷基化或芳基化的二氯铋烯反应，要么生成桥连物种，要么形成二铋烷。
