Department of Chemistry, Geology & Physics, 401 College Ave., Ashland University, Ashland, OH 44805, USA.
Department of Chemistry, Geology & Physics, 401 College Ave., Ashland University, Ashland, OH 44805, USA.
Sci Total Environ. 2021 Apr 10;764:142926. doi: 10.1016/j.scitotenv.2020.142926. Epub 2020 Oct 10.
The use of cadmium to produce inexpensive jewelry has recently been documented. Governments have adopted varying standards, with US states focused on either total cadmium content or extractable cadmium from children's jewelry, while the European Union has adopted a limit of 100 mg/kg cadmium for all jewelry. This study evaluated 80 items purchased at a discount jewelry store. The objective was to determine prevalence of cadmium in this jewelry, the amount of cadmium released by simulated mouthing or ingestion, and to confirm previous reports that damage to jewelry can increase cadmium release. Finally, a modified toxicity characteristic leaching procedure (TCLP) assessed the potential for jewelry to release cadmium after disposal. Thirty-two (40%) items showed detectable cadmium by X-ray fluorescence. Nine high‑cadmium pendants and rings with cadmium content ranging from 31.3 to 89.2% were subjected to extractions simulating mouthing or ingestion. Seven of nine items extracted in dilute saline to simulate mouthing released more than the US recommended maximum of 18 micrograms. Damaged jewelry released more cadmium for most items tested, with one ring yielding an average of 10,600 micrograms. Two pendants small enough to be swallowed were tested using dilute HCl to simulate ingestion. While one pendant did not release cadmium in excess of the US recommended maximum of 200 micrograms even when damaged, the other released an average of 63,100 micrograms after being damaged. Fourteen of fifteen samples of two high cadmium charms extracted using a modified TCLP extraction exceeded the 1.0 mg/L TCLP limit for cadmium, averaging 13.1 and 9.6 mg/L respectively for the two charms. These results demonstrate that high‑cadmium jewelry may pose a serious hazard if mouthed or ingested, and that regulatory standards that do not take into account the potential for increased release of cadmium resulting from damage to jewelry electroplating are inadequate.
最近有文献记录表明,镉被用于生产廉价珠宝。各国政府采用了不同的标准,美国各州侧重于儿童珠宝的总镉含量或可萃取镉,而欧盟则对所有珠宝采用了 100 毫克/千克镉的限量。本研究评估了在一家折扣珠宝店购买的 80 件商品。目的是确定这些珠宝中镉的存在情况、通过模拟咀嚼或吞食释放的镉量,并证实先前的报告,即珠宝损坏会增加镉的释放。最后,采用改良毒性特征浸出程序(TCLP)评估了珠宝在处置后释放镉的潜力。32 件(40%)物品通过 X 射线荧光检测出可检测到的镉。9 件高镉吊坠和戒指,镉含量范围为 31.3%至 89.2%,进行了模拟咀嚼或吞食的提取实验。9 件物品中有 7 件在模拟咀嚼的稀盐水中提取出的镉量超过了美国建议的最高值 18 微克。对于大多数测试的物品,损坏的珠宝释放出更多的镉,一个戒指的平均释放量为 10600 微克。两个小到可以吞下的吊坠用稀盐酸进行了测试,以模拟吞食。虽然一个吊坠即使损坏也没有释放超过美国建议的最高值 200 微克的镉,但另一个吊坠损坏后平均释放了 63100 微克。使用改良 TCLP 提取法对 14 个两个高镉小饰品的 15 个样本进行了测试,超过了 TCLP 对镉的 1.0 毫克/升限量,这两个小饰品的平均提取量分别为 13.1 和 9.6 毫克/升。这些结果表明,如果被咀嚼或吞食,高镉珠宝可能会造成严重危害,而且不考虑由于珠宝电镀损坏而导致镉释放增加的可能性的监管标准是不充分的。