Enhanced Movement of Two-Component Droplets on a Wedge-Shaped Ag/Cu Surface by a Wettability Gradient.

The wedge-shaped Ag/Cu surface with a contact angle (CA) [droplet of 30 vol % propylene glycol (PG)] of 18.6° in the wedge track and 64.6° at its periphery was fabricated through a facile gradient displacement reaction on the Cu substrate. The aqueous droplet of 30% PG could realize directed motion on the wedge track without back-end pinning, moving in a two-stage process of front-end spreading and subsequent back-end shrinking. A wettability gradient from 64.6 to 18.6° on the wedge surface could enhance the droplet motion, especially during the second stage. A favorable length of the wettability gradient (15 mm) was obtained, capable of moving the droplet the farthest displacement of 21.6 mm at a velocity of 0.53 mm/s on a wedge track with the wedge angle of α = 10° and length of 25 mm. The driving force arising from the wettability gradient during the second stage was evaluated theoretically to elucidate the effect of the length of the wettability gradient on the movement. Finally, three T-shaped self-driven surface micromixers composed of a mixing zone with uniform wettability and a transportation zone with different gradients were designed to test the drainage ability of droplets away from the surface. The wedge track combined with the wettability gradient was found to be capable of removing the mixed droplet completely out of the mixing region and flowing away, while the droplet would attach or stay in the mixing zone if actuated by the shape gradient or the wettability gradient alone.