Freund Ralph, Canossa Stefano, Cohen Seth M, Yan Wei, Deng Hexiang, Guillerm Vincent, Eddaoudi Mohamed, Madden David G, Fairen-Jimenez David, Lyu Hao, Macreadie Lauren K, Ji Zhe, Zhang Yuanyuan, Wang Bo, Haase Frederik, Wöll Christof, Zaremba Orysia, Andreo Jacopo, Wuttke Stefan, Diercks Christian S
Solid State Chemistry, University of Augsburg, 86159, Augsburg, Germany.
EMAT, University of Antwerp, 2020, Antwerp, Belgium.
Angew Chem Int Ed Engl. 2021 Nov 2;60(45):23946-23974. doi: 10.1002/anie.202101644. Epub 2021 Jul 9.
At its core, reticular chemistry has translated the precision and expertise of organic and inorganic synthesis to the solid state. While initial excitement over metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) was undoubtedly fueled by their unprecedented porosity and surface areas, the most profound scientific innovation of the field has been the elaboration of design strategies for the synthesis of extended crystalline solids through strong directional bonds. In this contribution we highlight the different classes of reticular materials that have been developed, how these frameworks can be functionalized, and how complexity can be introduced into their backbones. Finally, we show how the structural control over these materials is being extended from the molecular scale to their crystal morphology and shape on the nanoscale, all the way to their shaping on the bulk scale.
从本质上讲，网状化学已将有机和无机合成的精确性与专业技术应用于固态领域。虽然最初对金属有机框架（MOF）和共价有机框架（COF）的热情无疑源于它们前所未有的孔隙率和表面积，但该领域最深刻的科学创新在于精心设计了通过强定向键合成扩展晶体固体的策略。在本论文中，我们重点介绍了已开发的不同类型的网状材料、这些框架如何功能化以及如何在其骨架中引入复杂性。最后，我们展示了对这些材料的结构控制是如何从分子尺度扩展到纳米尺度的晶体形态和形状，直至宏观尺度的成型。
