Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310, UTM, Johor Bahru, Malaysia.
School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310, UTM, Johor Bahru, Johor, Malaysia; Centre of Hydrogen Energy, Institute of Future Energy, 81310, UTM, Johor Bahru, Johor, Malaysia.
Chemosphere. 2021 Aug;277:130285. doi: 10.1016/j.chemosphere.2021.130285. Epub 2021 Mar 22.
Carbon monoxide (CO) is the most harmful pollutant in the air, causing environmental issues and adversely affecting humans and the vegetation and then raises global warming indirectly. CO oxidation is one of the most effective methods of reducing CO by converting it into carbon dioxide (CO) using a suitable catalytic system, due to its simplicity and great value for pollution control. The CO oxidation reaction has been widely studied in various applications, including proton-exchange membrane fuel cell technology and catalytic converters. CO oxidation has also been of great academic interest over the last few decades as a model reaction. Many review studies have been produced on catalysts development for CO oxidation, emphasizing noble metal catalysts, the configuration of catalysts, process parameter influence, and the deactivation of catalysts. Nevertheless, there is still some gap in a state of the art knowledge devoted exclusively to synergistic interactions between catalytic activity and physicochemical properties. In an effort to fill this gap, this analysis updates and clarifies innovations for various latest developed catalytic CO oxidation systems with contemporary evaluation and the synergistic relationship between oxygen vacancies, strong metal-support interaction, particle size, metal dispersion, chemical composition acidity/basicity, reducibility, porosity, and surface area. This review study is useful for environmentalists, scientists, and experts working on mitigating the harmful effects of CO on both academic and commercial levels in the research and development sectors.
一氧化碳(CO)是空气中最有害的污染物,它不仅造成环境问题,还会对人类和植被造成不利影响,从而间接导致全球变暖。CO 氧化是减少 CO 的最有效方法之一,通过使用合适的催化系统将其转化为二氧化碳(CO ),由于其简单性和在污染控制方面的巨大价值而备受关注。CO 氧化反应在各种应用中得到了广泛研究,包括质子交换膜燃料电池技术和催化转化器。几十年来,CO 氧化作为一种模型反应引起了学术界的极大兴趣。已经有许多关于 CO 氧化催化剂开发的综述研究,强调了贵金属催化剂、催化剂的结构、工艺参数的影响以及催化剂的失活。然而,在专门致力于催化活性和物理化学性质协同相互作用的最新知识状态方面,仍然存在一些差距。为了填补这一空白,本分析更新并澄清了各种最新开发的催化 CO 氧化系统的创新,包括当代评估以及氧空位、强金属-载体相互作用、粒径、金属分散度、化学组成酸度/碱性、还原性、孔隙率和表面积之间的协同关系。这项综述研究对于环保主义者、科学家以及在研究和开发领域从事减轻 CO 对学术和商业层面的有害影响的专家都非常有用。