苯硫酚盐的亲核反应活性。
Nucleophilic Reactivities of Thiophenolates.
作者信息
Jüstel Patrick M, Pignot Cedric D, Ofial Armin R
机构信息
Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, 81377 München, Germany.
出版信息
J Org Chem. 2021 Apr 16;86(8):5965-5972. doi: 10.1021/acs.joc.1c00025. Epub 2021 Apr 2.
The nucleophilic reactivities of substituted thiophenolates were determined by following the kinetics of their reactions with a series of quinone methides (reference electrophiles) in DMSO at 20 °C. The experimentally determined second-order rate constants were analyzed according to the Mayr-Patz equation log = ( + ) to derive the nucleophile-specific reactivity parameters and for ten thiophenolate ions.
通过在20°C下于二甲基亚砜（DMSO）中跟踪一系列取代硫酚盐与醌甲基化物（参考亲电试剂）的反应动力学，测定了取代硫酚盐的亲核反应活性。根据迈尔 - 帕茨方程log = ( + ) 对实验测定的二级速率常数进行分析，以得出十种硫酚盐离子的亲核试剂特异性反应参数 和 。
Zotero 插件