Tailoring the Effects of Titanium Dioxide (TiO) and Polyvinyl Alcohol (PVA) in the Separation and Antifouling Performance of Thin-Film Composite Polyvinylidene Fluoride (PVDF) Membrane.

In this study, thin-film composite (TFC) polyvinylidene fluoride (PVDF) membranes were synthesized by coating with titanium dioxide (TiO)/polyvinyl alcohol (PVA) solution by a dip coating method and cross-linked with glutaraldehyde. Glutaraldehyde (GA) acted as a cross-linking agent to improve the thermal and chemical stability of the thin film coating. The incorporation of TiO in the film enhanced the hydrophilicity of the membrane and the rejection of dyes during filtration. The layer of TiO nanoparticles on the PVDF membranes have mitigated the fouling effects compared to the plain PVDF membrane. The photocatalytic performance was studied at different TiO loading for the photodegradation of dyes (reactive blue (RB) and methyl orange (MO)). The results indicated that the thin film coating of TiO/PVA enhanced photocatalytic performance and showed good reusability under UV irradiation. This study showed that nearly 78% MO and 47% RB were removed using the TFC membrane. This work provides a new vision in the fabrication of TFC polymeric membranes as an efficient wastewater treatment tool.