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解决玉米秸秆废弃物与沥青资源短缺的绿色方案:水热碳化制备的水炭作为沥青结合料新型性能增强剂

Greener Solution to Waste Corn Stalks and Shortage of Asphalt Resource: Hydrochar Produced by Hydrothermal Carbonization as a Novel Performance Enhancer for Asphalt Binder.

作者信息

Wu Xiaoming, Hu Chichun

机构信息

School of Civil Engineering and Transportation, South China University of Technology, Guangzhou 510641, China.

出版信息

Materials (Basel). 2021 Mar 15;14(6):1427. doi: 10.3390/ma14061427.

Abstract

Utilization of waste corn stalks (CS) has seized extensive attention due to high annual output and hazardous impact of piling aside or direct combustion on environment. However, previously there has been a lot of emphasis on improvement of its energy efficiency as solid fuel while limited investigations are available which explore the possibility of applying corn stalks as performance enhancer in asphalt binder. The purpose of this study is to examine the potential of employing hydrochar as modifiers in asphalt binder by a series of experimental tests. In this study, two hydrochar were produced from corn stalks by a novel process called hydrothermal carbonization at a different reaction temperature. The two hydrochar and their responding hydrochar-modified asphalt (HCMA) were tested by chemical and rheological tests. Chemical analysis detected the interaction between hydrochar and binder factions, resulting in poor compatibility but satisfying anti-aging property. Even though hydrochar increased the viscosity of bitumen, implying worse workability, and caused poor storage stability, ameliorated performance of asphalt binder at high temperature by incorporating hydrochar was verified by various criteria such as higher performance grade (PG) failure temperature and lower non-recoverable creep compliance (). Moreover, higher reaction temperature makes hydrochar's particles smaller and more homogeneous, which results in slightly lower enhanced high temperature performance, more satisfying workability, better storage stability, and greater anti-aging effect of hydrochar-modified asphalt. Eventually, this study provided a promising win-win solution to environment problems concerning corn stalk treatment and shortage of asphalt binder. Further exploration of methods to improve HCMA's storage stability, real-scale corroboration on trial section and life cycle assessment of asphalt pavement containing hydrochar modifiers will be followed in the future.

摘要

废弃玉米秸秆(CS)的利用因其年产量高以及堆积或直接燃烧对环境的有害影响而备受广泛关注。然而,此前很多研究都着重于提高其作为固体燃料的能源效率,而探索将玉米秸秆用作沥青结合料性能增强剂的研究却很有限。本研究的目的是通过一系列实验测试来检验采用水热炭作为沥青结合料改性剂的潜力。在本研究中,通过一种名为水热碳化的新工艺,在不同反应温度下由玉米秸秆制备了两种水热炭。对这两种水热炭及其相应的水热炭改性沥青(HCMA)进行了化学和流变学测试。化学分析检测了水热炭与结合料组分之间的相互作用,结果表明相容性较差,但抗老化性能良好。尽管水热炭增加了沥青的粘度,意味着施工性能变差,且导致储存稳定性不佳,但通过各种标准,如更高的性能等级(PG)失效温度和更低的不可恢复蠕变柔量( ),证实了加入水热炭可改善沥青结合料在高温下的性能。此外,更高的反应温度使水热炭颗粒更小且更均匀,这导致水热炭改性沥青的高温性能增强略有降低、施工性能更令人满意、储存稳定性更好以及抗老化效果更佳。最终,本研究为解决玉米秸秆处理的环境问题和沥青结合料短缺问题提供了一种有前景的双赢解决方案。未来将进一步探索提高HCMA储存稳定性的方法、在试验路段进行实际规模验证以及对含水性炭改性剂的沥青路面进行生命周期评估。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/083e/8001865/5c308209eb3c/materials-14-01427-g001.jpg

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