Xu Chi, Wang Duanyi, Zhang Shaowei, Guo Enbei, Luo Haoyang, Zhang Zeyu, Yu Huayang
School of Civil Engineering and Transportation, South China University of Technology, Wushan Road, Tianhe District, Guangzhou 510000, China.
Institute of Highway Engineering, RWTH Aachen University, Mies-van-der-Rohe-Street 1, 52074 Aachen, Germany.
Polymers (Basel). 2021 Mar 29;13(7):1083. doi: 10.3390/polym13071083.
Lignin accounts for approximately 30% of the weight of herbaceous biomass. Utilizing lignin in asphalt pavement industry could enhance the performance of pavement while balancing the construction cost. This study aims to evaluate the feasibility of utilizing lignin as a bitumen performance improver. For this purpose, lignin derived from aspen wood chips (labeled as KL) and corn stalk residues (labeled as CL) were selected to prepare the lignin modified bituminous binder. The properties of the lignin modified binder were investigated through rheological, mechanical and chemical tests. The multiple stress creep recovery (MSCR) test results indicated that adding lignin decreased the J of based binder by a range of 8% to 23% depending on the stress and lignin type. Lignin showed a positive effect on the low temperature performance of asphalt binder, because at -18 °C, KL and CL were able to reduce the stiffness of base binder from 441 MPa to 369 MPa and 378 MPa, respectively. However, lignin was found to deteriorate the fatigue life and workability of base binder up to 30% and 126%. With bituminous mixture, application of lignin modifiers improved the Marshall Stability and moisture resistance of base mixture up to 21% and 13%, respectively. Although, adding lignin modifiers decreased the molecular weight of asphalt binder according to the gel permeation chromatography (GPC) test results. The Fourier-transform infrared spectroscopy (FTIR) test results did not report detectable changes in functional group of based binder.
木质素约占草本生物质重量的30%。在沥青路面行业利用木质素可以提高路面性能,同时平衡建设成本。本研究旨在评估利用木质素作为沥青性能改进剂的可行性。为此,选择了源自白杨木屑(标记为KL)和玉米秸秆残渣(标记为CL)的木质素来制备木质素改性沥青结合料。通过流变学、力学和化学试验研究了木质素改性结合料的性能。多重应力蠕变恢复(MSCR)试验结果表明,添加木质素会使基础结合料的J值降低8%至23%,具体取决于应力和木质素类型。木质素对沥青结合料的低温性能有积极影响,因为在-18℃时,KL和CL能够分别将基础结合料的刚度从441MPa降低到369MPa和378MPa。然而,发现木质素会使基础结合料的疲劳寿命和工作性能分别降低30%和126%。对于沥青混合料,使用木质素改性剂可使基础混合料的马歇尔稳定度和抗湿性分别提高21%和13%。尽管根据凝胶渗透色谱(GPC)试验结果,添加木质素改性剂会降低沥青结合料的分子量。傅里叶变换红外光谱(FTIR)试验结果未报告基础结合料官能团有可检测到的变化。