Li Wenzhu, Zhang Jing, Huang Jingda, Shao Yuanchao, Zhang Wenbiao, Dai Chunping
School of Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Department of Wood Science, Faculty of Forestry, University of British Columbia, 2900-2424 Main Mall, Vancouver, BC V6T 1Z4, Canada.
Materials (Basel). 2021 Mar 20;14(6):1524. doi: 10.3390/ma14061524.
Due to its excellent adsorption and humidity control function, bamboo charcoal (BC) has often been mixed with polypropylene (PP) to produce PP/BC composites for interior paneling applications. However, due to the poor foaming quality of PP, PP/BC composites suffer as a result of their high density, which limits their scope of use. Here, to improve its foaming quality, PP was modified with ethylene vinyl acetate (EVA), and then the EVA-modified PP (E-PP) was mixed with different contents of BC (0 wt.%-50 wt.%), as well as foaming agent (Azodicarbonamide, AC) and its auxiliaries (ZnO, Znst), in a twin-screw extruder, followed by hot-pressing at high temperature to obtain foamed E-PP/BC composites. The resulting composites showed good porosity and pore distribution with an increase of BC content by up to 20%. Further increase in the BC content seemed to cause the foaming performance to decrease significantly. The product density and adsorption rate increased, while the mechanical strength decreased with increasing BC content. At a BC content of 40 wt.%, the foamed E-PP/BC composite showed the best combined performance, with a density of 0.90 g/cm, 24-h formaldehyde adsorption rate of 0.48, and bending strength of 11.59 MPa.
由于竹炭(BC)具有优异的吸附和湿度控制功能,它常与聚丙烯(PP)混合以生产用于室内镶板的PP/BC复合材料。然而,由于PP的发泡质量较差,PP/BC复合材料因密度高而受到影响,这限制了它们的使用范围。在此,为了提高其发泡质量,用乙烯-醋酸乙烯酯(EVA)对PP进行改性,然后将EVA改性的PP(E-PP)与不同含量的BC(0 wt.% - 50 wt.%)以及发泡剂(偶氮二甲酰胺,AC)及其助剂(ZnO、硬脂酸锌)在双螺杆挤出机中混合,随后在高温下热压以获得发泡的E-PP/BC复合材料。随着BC含量增加至20%,所得复合材料显示出良好的孔隙率和孔隙分布。BC含量的进一步增加似乎导致发泡性能显著下降。随着BC含量的增加,产品密度和吸附率增加,而机械强度下降。在BC含量为40 wt.%时,发泡的E-PP/BC复合材料表现出最佳的综合性能,密度为0.90 g/cm,24小时甲醛吸附率为0.48,弯曲强度为11.59 MPa。