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聚合物共混物对发泡木塑复合材料性能的影响。

Effect of Polymer Blends on the Properties of Foamed Wood-Polymer Composites.

作者信息

Wang Suwei, Xue Ping, Jia Mingyin, Tian Jing, Zhang Run

机构信息

College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China.

出版信息

Materials (Basel). 2019 Jun 19;12(12):1971. doi: 10.3390/ma12121971.

Abstract

The polypropylene (PP)/wood flour (WF) composites were prepared using a co-rotating twin-screw extruder followed by a single-screw extruder foaming system in this paper. Polymers, such as polyolefin elastomer (POE), high-density polyethylene (HDPE) or microcrystalline wax, were blended with PP in the preparation of composites to improve the melt strength. And a cavity transfer mixer was introduced to increase the distribution uniformity of components in composites. Meanwhile, the effect of the polymer blends on the microstructure and mechanical properties of samples was investigated. The experimental results show that the addition of POE and HDPE resulted in the second melting peak in the differential scanning calorimeter (DSC) curves and a great decrease in the cell size was caused by the added POE. However, due to the velocity difference of composites in the die, the shape of bubbles gradually became irregular. Moreover, the impact strength of samples significantly increased by 85% for the added POE and the apparent density decreased by 6.7%. And the minimum Vicat softening temperature of 133.7 °C was obtained when the mass ratio of HDPE to PP was 4/6.

摘要

本文采用同向旋转双螺杆挤出机,随后通过单螺杆挤出机发泡系统制备了聚丙烯(PP)/木粉(WF)复合材料。在复合材料制备过程中,将聚烯烃弹性体(POE)、高密度聚乙烯(HDPE)或微晶蜡等聚合物与PP共混,以提高熔体强度。并引入了熔体分配混合器,以提高复合材料中各组分的分布均匀性。同时,研究了聚合物共混物对样品微观结构和力学性能的影响。实验结果表明,POE和HDPE的加入导致差示扫描量热仪(DSC)曲线出现第二个熔融峰,POE的加入使泡孔尺寸大幅减小。然而,由于复合材料在模头中的流速差异,气泡形状逐渐变得不规则。此外,添加POE后样品的冲击强度显著提高了85%,表观密度降低了6.7%。当HDPE与PP的质量比为4/6时,获得了最低维卡软化温度133.7℃。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0077/6630291/5c60d9a6c496/materials-12-01971-g001.jpg

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