Kumar Deepak, Vaya Dipti, Chundawat Tejpal Singh
Department of Chemistry, Amity University, Gurgaon, Haryana am-122017, India.
Department of Applied Sciences, The North Cap University, Sector 23-A, Gurgaon, Haryana 122017, India.
ACS Omega. 2021 Mar 27;6(13):8933-8941. doi: 10.1021/acsomega.0c06202. eCollection 2021 Apr 6.
Total synthesis of a new β-carboline alkaloid, 6-hydroxymetatacarboline-d, which was isolated from fruiting bodies of was accomplished in 14 steps. The synthetic strategy features the Pictet-Spengler reaction to construct the tricyclic core followed by amide coupling and the Horner-Wadsworth-Emmons reaction.
从[某种真菌]子实体中分离得到的一种新的β-咔啉生物碱6-羟基间位塔卡啉-d的全合成以14步完成。合成策略的特点是通过Pictet-Spengler反应构建三环核心，随后进行酰胺偶联和Horner-Wadsworth-Emmons反应。 （注：原文中“from fruiting bodies of ”这里缺少具体物种信息）
