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AlO(0001)上类锡烯纳米片的光学性质:对二维过渡金属碳化物和氮化物光子学的启示

Optical Properties of Stanene-like Nanosheets on AlO(0001): Implications for Xene Photonics.

作者信息

Grazianetti Carlo, Bonaventura Eleonora, Martella Christian, Molle Alessandro, Lupi Stefano

机构信息

CNR-IMM Unit of Agrate Brianza, via C. Olivetti 2, Agrate Brianza I-20864, Italy.

CNR-IOM Dipartimento di Fisica, Sapienza Università di Roma, P.le Aldo Moro 2, Roma I-00185, Italy.

出版信息

ACS Appl Nano Mater. 2021 Mar 26;4(3):2351-2356. doi: 10.1021/acsanm.0c03221. Epub 2021 Mar 10.

Abstract

Stanene is one of the most intriguing two-dimensional (2D) materials because of its nontrivial topological properties. Here, the optical properties from THz to UV of molecular beam deposited tin nanosheets on AlO(0001) are reported. The experimental absorption coefficient cannot be described in terms of metallic tin or tin oxides. Nonetheless, a similar optical behavior was predicted by theory for freestanding stanene, thus suggesting the formation of the 2D tin nanosheets with stanene-like properties. These findings show that 2D tin bears appealing optical properties in a broad range of the electromagnetic spectrum, thus paving the way to Xenes-based nanophotonics.

摘要

由于其非平凡的拓扑性质,锡烯是最引人入胜的二维材料之一。在此,报道了在AlO(0001)上分子束沉积的锡纳米片从太赫兹到紫外波段的光学性质。实验吸收系数无法用金属锡或氧化锡来描述。尽管如此,理论预测独立的锡烯会有类似的光学行为,这表明形成了具有类似锡烯性质的二维锡纳米片。这些发现表明二维锡在很宽的电磁光谱范围内具有吸引人的光学性质,从而为基于烯类材料的纳米光子学铺平了道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cff9/8023281/db451ac9d3bd/an0c03221_0001.jpg

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