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以糊精-聚丙烯酰胺和硼酸为基础的坚韧透明、自修复、高吸水性薄膜的合成。

Synthesis of dextrin-polyacrylamide and boric acid based tough and transparent, self-healing, superabsorbent film.

机构信息

Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar 144 011, Punjab, India.

出版信息

Int J Biol Macromol. 2021 Jul 1;182:712-721. doi: 10.1016/j.ijbiomac.2021.04.028. Epub 2021 Apr 16.

Abstract

Stretchabiliy, transparency and self-healing ability of bio-based materials are some of the important features for their utilization in the biomedical field. Recently, robust self-healing super porous materials possessing multifunctional nature have raised enormous interest among the researchers in order to design different materials which can be used in industrial, biomedical and pharmaceutical fields. Herein, a novel self-healing, stretchable and transparent superabsorbent film based on Dextrin-polyacrylamide and Boric Acid (D-cl-polyAAm) was synthesized using a free radical reaction mechanism. In distilled water, the maximum water absorptivity of the synthesized film was reported to be 3156% after the optimization of various reaction parameters. The film was also found to show structural integrity in urea solution, phosphate buffer and solutions of different pH. Lastly, the viscoelastic and self-healing analysis of the film suggested its utility towards biomedical field.

摘要

生物基材料的拉伸性、透明度和自修复能力是其在生物医学领域应用的一些重要特性。最近,具有多功能特性的坚固自修复超多孔材料引起了研究人员的极大兴趣,以便设计可用于工业、生物医学和制药领域的不同材料。在此,使用自由基反应机制合成了一种基于糊精-聚丙烯酰胺和硼酸(D-cl-polyAAm)的新型自修复、拉伸和透明的超吸水性薄膜。在蒸馏水中,通过优化各种反应参数,合成膜的最大吸水率报道为 3156%。该薄膜在尿素溶液、磷酸盐缓冲液和不同 pH 值的溶液中也表现出结构完整性。最后,对薄膜的粘弹性和自修复分析表明其可用于生物医学领域。

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