Study on surface enhanced Raman scattering of Au and Au@AlO spherical dimers based on 3D finite element method.

In this paper, the surface enhanced Raman scattering (SERS) characteristics of Au and Au@AlO nanoparticle dimers were calculated and analyzed by using finite element method (3D-FEM). Firstly, the electric field enhancement factors of Au nanoparticles at the dimer gap were optimized from three aspects: the incident angle of the incident light, the radius of nanoparticle and the distance of the dimer. Then, aluminum oxide is wrapped on the Au dimer. What is different from the previous simulation is that AlO shell and Au core are regarded as a whole and the total radius of Au@AlO dimer is controlled to remain unchanged. By comparing the distance of Au nucleus between Au and Au@AlO dimer, it is found that the electric field enhancement factor of Au@AlO dimer is much greater than that of Au dimer with the increase of AlO thickness. The peak of electric field of Au@AlO dimer moves towards the middle of the resonance peak of the two materials, and it is more concentrated than that of the Au dimer. The maximum electric field enhancement factor 583 is reached at the shell thickness of 1 nm. Our results provide a theoretical reference for the design of SERS substrate and the extension of the research scope.