前所未有的单官能化β-安德森簇：[RRC(CHO)MnWO]，一类新型无机连接体的潜在候选物。
Unprecedented monofunctionalized β-Anderson clusters: [RRC(CHO)MnWO], a class of potential candidates for new inorganic linkers.
作者信息
Li Qi, Wei Yongge
机构信息
Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
出版信息
Chem Commun (Camb). 2021 Apr 25;57(32):3865-3868. doi: 10.1039/d1cc00563d. Epub 2021 Mar 30.
PMID:33871508
Abstract
Novel Anderson-type polyoxomanganotungstate clusters with the β-isomer structure, [{RRC(CHO)}MnWO], were synthesized and monofunctionalized with derivatives of 1,3-propanediol via a one-pot strategy, and show unprecedented coordination activity as non-lacunary polyoxotungstate clusters and could have potential in the future construction of POM-frameworks.
摘要
具有β-异构体结构的新型安德森型聚氧锰钨酸盐簇合物[{RRC(CHO)}MnWO]通过一锅法合成，并通过1,3-丙二醇衍生物进行单官能化，作为非缺位聚氧钨酸盐簇合物展现出前所未有的配位活性，并且在未来的多金属氧酸盐框架构建中可能具有潜力。
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