Department of Chemistry, Tsinghua University, Beijing 100062, China.
School of Chemistry and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China.
Molecules. 2022 Aug 16;27(16):5212. doi: 10.3390/molecules27165212.
Anderson-type ([XMO]) polyoxometalates (POMs) are a class of polymetallic-oxygen cluster inorganic compounds with special structures and properties. They have been paid extensive attention by researchers now, due to their chemical modification and designability, which have been widely applied in the fields of materials, catalysis and medicine. In contemporary years, the application of Anderson-type POMs in catalytic organic oxidation reaction has gradually shown great significance for the research of green catalytic process. In this paper, we investigate the application of Anderson-type POMs in organic synthesis reaction, and these works are summarized according to the different structure of POMs. This will provide a new strategy for further investigation of the catalytic application of Anderson-type POMs and the study of green catalysis.
安德森型([XMO])多金属氧酸盐(POMs)是一类具有特殊结构和性质的多金属-氧簇无机化合物。由于其化学修饰和设计的可变性，它们已经引起了研究人员的广泛关注，并被广泛应用于材料、催化和医学等领域。近年来，安德森型 POMs 在催化有机氧化反应中的应用逐渐显示出对绿色催化过程研究的重要意义。本文研究了安德森型 POMs 在有机合成反应中的应用，并根据 POMs 的不同结构对这些工作进行了总结。这将为进一步研究安德森型 POMs 的催化应用和绿色催化提供新的策略。
