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石墨烯/HS-TiO₂纳米复合材料的湿度传感特性评估

Evaluation Humidity Sensing Properties of Graphene/HS-TiO₂ Nanocomposites.

作者信息

Zhu Zhen, Lin Wang-De

机构信息

School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384, China.

Department of Center for General Education, St. Mary's Junior College of Medicine, Nursing and Management, Yilan 26647, Taiwan.

出版信息

J Nanosci Nanotechnol. 2021 Oct 1;21(10):5143-5149. doi: 10.1166/jnn.2021.19446.

Abstract

This paper reports on a nanocomposite synthesized by sol-gel procedure comprising graphene sheets with hollow spheres of titanium dioxide (G/HS-TiO₂) with varying weight percentages of graphene for the purpose of humidity sensors. The surface morphology of the nanocomposite was characterized using transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). The structural properties were examined using X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). The response to 12-80% RH at room temperature exhibited sensitivity ( = 135). However, the relative humidity range of 12-90% at room temperature exhibited higher sensitivity ( = 557). Sensors fabricated using the proposed nanocomposite exhibited high sensitivity to humidity, high stability, rapid response times, and rapid recovery times with hysteresis error of less than 1.79%. These results demonstrate the outstanding potential of his material for the monitoring of atmospheric humidity. This study also sought to elucidate the mechanisms underlying humidity sensing performance.

摘要

本文报道了一种通过溶胶-凝胶法合成的纳米复合材料,该复合材料由石墨烯片与二氧化钛空心球(G/HS-TiO₂)组成,其中石墨烯的重量百分比各不相同,用于制造湿度传感器。使用透射电子显微镜(TEM)和能量色散X射线光谱(EDX)对该纳米复合材料的表面形态进行了表征。使用X射线衍射(XRD)和傅里叶变换红外光谱(FTIR)对其结构特性进行了研究。在室温下对12-80%相对湿度的响应显示出灵敏度(=135)。然而,在室温下12-90%的相对湿度范围内表现出更高的灵敏度(=557)。使用所提出的纳米复合材料制造的传感器对湿度表现出高灵敏度、高稳定性、快速响应时间和快速恢复时间,滞后误差小于1.79%。这些结果证明了这种材料在监测大气湿度方面的巨大潜力。本研究还试图阐明湿度传感性能背后的机制。

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