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多功能透明聚氨酯薄膜的开发与特性。

Development and Characteristics of Multipurpose Transparent Polyurethane Film.

机构信息

ICT Device Packaging Research Center, Korea Electronics Technology Institute (KETI), Bundang-gu, Seongnam-si, Gyeonggi-do, 13509, Korea.

Graduate School of Nano IT Design Fusion, Seoul National University of Science and Technology Seoul, 139-743, Korea.

出版信息

J Nanosci Nanotechnol. 2021 Oct 1;21(10):5222-5228. doi: 10.1166/jnn.2021.19445.

Abstract

In industry, recent research developments include flexible films and foldable films. The next step is the development of stretchable films, and studies are being intensively carried out. Research on the development of stretchable and transparent materials is also increasing greatly. Currently, polydimethylsiloxane (PDMS) is the most commonly used film in the industry. However, PDMS surfaces are hydrophobic, so their use is limited to making materials and compounds with hydrophilic properties. In this study, we developed a transparent polyurethane film that can be used for multiple purposes. A transparency comparison between the transparent polyurethane film and the general polyurethane film was used to verify their future application. The conventional polyurethane films showed a transmittance rate of 2.2 percent, but the transparent polyurethane films achieved a high transmittance rate of 85 percent. To determine whether the film can be realized, we produced a conductive paste using resin for the transparent polyurethane film. In addition, a conductive paste was made based on the material used in the transparent polyurethane film to verify the hardness and reliability of the adhesion of electrodes, and we confirmed this with thermogravimetric analysis (TGA). The transparent polyurethane based paste was made with stretchable electrodes through a screen printing method. The manufactured stretchable electrodes were demonstrated by mechanical and adhesion tests. Finally, a permittivity test was conducted to determine the suitability of the film for application to printed electrodes for antennas in the future. The genetic rate of transparent polyurethane films was better than that of conventional polyurethane films. Moreover, the adhesion of the transparent polyurethane film and stretchable electrodes was as good as that of conventional polyurethane film and stretchable electrodes, and observation by optical microscopy confirmed that the printing performance was also excellent. In addition, the conductive paste made based on the transparent polyurethane film material was cured for 1 hour at 120 °C, and TGA analysis confirmed that both the binders and curing agent responded well in the test for curing the developed stretchable electrodes and transparent polyurethane.

摘要

在工业领域,最近的研究进展包括柔性薄膜和可折叠薄膜。下一步是开发可拉伸薄膜,目前正在进行深入研究。可拉伸透明材料的研究也在大幅增加。目前,聚二甲基硅氧烷(PDMS)是工业中最常用的薄膜。然而,PDMS 表面是疏水的,因此其用途仅限于制造具有亲水性的材料和化合物。在这项研究中,我们开发了一种可用于多种用途的透明聚氨酯薄膜。通过透明聚氨酯薄膜与普通聚氨酯薄膜的透明度比较,验证了它们未来的应用。常规聚氨酯薄膜的透光率为 2.2%,而透明聚氨酯薄膜的透光率高达 85%。为了确定薄膜是否可以实现,我们使用树脂为透明聚氨酯薄膜制作了一种导电糊。此外,还根据透明聚氨酯薄膜的材料制作了一种导电糊,以验证电极的硬度和附着力的可靠性,并通过热重分析(TGA)进行了确认。通过丝网印刷法,使用透明聚氨酯基糊剂制作了可拉伸电极。通过机械和附着力测试对制造的可拉伸电极进行了演示。最后,进行了介电常数测试,以确定该薄膜是否适合未来应用于印刷天线的电极。透明聚氨酯薄膜的遗传率优于普通聚氨酯薄膜。此外,透明聚氨酯薄膜与可拉伸电极的附着力与普通聚氨酯薄膜和可拉伸电极的附着力一样好,光学显微镜观察证实其印刷性能也非常出色。此外,基于透明聚氨酯膜材料的导电糊在 120°C 下固化 1 小时,TGA 分析确认开发的可拉伸电极和透明聚氨酯用的粘合剂和固化剂在测试中反应良好。

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