Department of Chemistry and Biochemistry and California NanoSystems Institute, University of California, Los Angeles, California 90095, United States.
Physical Sciences and Engineering Division, Catalysis Center, King Abdullah University of Science and Technology, 23955-6900 Thuwal, Kingdom of Saudi Arabia.
Nano Lett. 2021 May 12;21(9):3699-3707. doi: 10.1021/acs.nanolett.1c00968. Epub 2021 Apr 22.
Conjugated polyaniline can impact the field of water filtration membranes due to its hydrophilic and antibacterial nature, facile and inexpensive synthesis procedure, heat and acid tolerance, and unique doping/dedoping chemistry. However, the gelation effect, its rigid backbone, and the limited hydrophilicity of polyaniline severely restrict the adaptability to membranes and their antifouling performance. This Mini Review summarizes important works of polyaniline-related ultrafiltration membranes, highlighting solutions to conquer engineering obstacles in processing and challenges in enhancing surface hydrophilicity with an emphasis on chemistry. As a pH-responsive polymer convertible to a conductive salt, this classic material should continue to bring unconventional advances into the realm of water filtration membranes.
聚联苯胺由于其亲水性和抗菌性、简便且廉价的合成工艺、耐热耐酸以及独特的掺杂/脱掺杂化学性质,可能会对水过滤膜领域产生影响。然而,聚联苯胺的凝胶效应、刚性主链和有限的亲水性严重限制了其对膜的适应性和抗污性能。这篇 Mini Review 总结了与聚联苯胺相关的超滤膜的重要工作,重点介绍了克服加工工程障碍和提高表面亲水性的解决方案,强调了化学在其中的作用。作为一种可转化为导电盐的 pH 响应聚合物,这种经典材料应该继续为水过滤膜领域带来非常规的进展。