Zhu Weihao, Gunnoe T Brent
Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States.
J Am Chem Soc. 2021 May 12;143(18):6746-6766. doi: 10.1021/jacs.1c01810. Epub 2021 Apr 28.
On a large scale, the dominant method to produce alkyl arenes has been arene alkylation from arenes and olefins using acid-based catalysis. The addition of arene C-H bonds across olefin C═C bonds catalyzed by transition-metal complexes through C-H activation and olefin insertion into metal-aryl bonds provides an alternative approach with potential advantages. This Perspective presents recent developments of olefin hydroarylation and oxidative olefin hydroarylation catalyzed by molecular complexes based on group 10 transition metals (Ni, Pd, Pt). Emphasis is placed on comparisons between Pt catalysts and other group 10 metal catalysts as well as Ru, Ir, and Rh catalysts.
从大规模来看，生产烷基芳烃的主要方法一直是使用酸催化使芳烃与烯烃进行芳烃烷基化反应。过渡金属配合物通过C-H活化催化芳烃C-H键加成到烯烃C═C键上，并使烯烃插入金属-芳基键中，提供了一种具有潜在优势的替代方法。本综述介绍了基于第10族过渡金属（镍、钯、铂）的分子配合物催化烯烃氢芳基化反应和氧化烯烃氢芳基化反应的最新进展。重点是铂催化剂与其他第10族金属催化剂以及钌、铱和铑催化剂之间的比较。
