Xie Zhaoyu, Atherton Timothy J
Department of Physics and Astronomy, Tufts University, 574 Boston Avenue, Medford, Massachusetts 02155, USA.
Soft Matter. 2021 Apr 28;17(16):4426-4433. doi: 10.1039/d0sm02174a.
We examine the regime between crystalline and amorphous packings of anisotropic objects on surfaces of different genus by continuously varying their size distribution or shape from monodispersed spheres to bidispersed mixtures or monodispersed ellipsoidal particles; we also consider an anisotropic variant of the Thomson problem with a mixture of charges. With increasing anisotropy, we first observe the disruption of translational order with an intermediate orientationally ordered hexatic phase as proposed by Nelson, Rubinstein and Spaepen, and then a transition to amorphous state. By analyzing the structure of the disclination motifs induced, we show that the hexatic-amorphous transition is caused by the growth and connection of disclination grain boundaries, suggesting this transition lies in the percolation universality class in the scenarios considered.
我们通过连续改变各向异性物体的尺寸分布或形状(从单分散球体到双分散混合物或单分散椭球形颗粒),研究不同亏格曲面上各向异性物体的晶体与非晶体堆积之间的状态;我们还考虑了带有电荷混合物的汤姆森问题的各向异性变体。随着各向异性的增加,我们首先观察到平移有序的破坏,出现了如尼尔森、鲁宾斯坦和斯帕彭所提出的具有中间取向有序六次相,然后转变为非晶态。通过分析所诱导的位错图案的结构,我们表明六次相 - 非晶态转变是由位错晶界的生长和连接引起的,这表明在所考虑的情形中,这种转变属于渗流普适类。