Islam Md Jahidul, Kitagawa Yuichi, Tsurui Makoto, Hasegawa Yasuchika
Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Kita-21, Nishi-10, Sapporo, Hokkaido 001-0021, Japan.
Graduate School of Chemical Sciences and Engineering, Hokkaido University, Kita-13, Nishi-8, Sapporo, Hokkaido 060-8628, Japan.
Dalton Trans. 2021 Apr 28;50(16):5433-5436. doi: 10.1039/d1dt00519g.
This paper reports chiral mixed Eu(iii)-Ln(iii) coordination polymers (Ln = Gd and Sm) with a high dissymmetry factor of circularly polarized luminescence (gCPL = 0.15) for the enhancement of the emission quantum yield (Φtot ≥ 50%), achieved via control of 4f electronic structures.
本文报道了通过控制4f电子结构实现的手性混合铕（III）-镧系（III）配位聚合物（Ln = 钆和钐），其具有高圆偏振发光不对称因子（gCPL = 0.15），以提高发射量子产率（Φtot≥50%）。
