Curran Daniel J, Ganguly Gaurab, Heit Yonaton N, Wolford Nikki J, Minasian Stefan G, Löble Matthias W, Cary Samantha K, Kozimor Stosh A, Autschbach Jochen, Neidig Michael L
Department of Chemistry, University of Rochester, Rochester, New York 14627, USA.
Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260, USA.
Dalton Trans. 2021 Apr 28;50(16):5483-5492. doi: 10.1039/d1dt00513h.
C-term magnetic circular dichroism (MCD) spectroscopy is a powerful method for probing d-d and f-f transitions in paramagnetic metal complexes. However, this technique remains underdeveloped both experimentally and theoretically for studies of U(v) complexes of Oh symmetry, which have been of longstanding interest for probing electronic structure, bonding, and covalency in 5f systems. In this study, C-term NIR MCD of the Laporte forbidden f-f transitions of [UCl6]- and [UF6]- are reported, demonstrating the significant fine structure resolution possible with this technique including for the low energy Γ7 → Γ8 transitions in [UF6]-. The experimental NIR MCD studies were further extended to [U(OC6F5)6]-, [U(CH2SiMe3)6]-, and [U(NC(tBu)(Ph))6]- to evaluate the effects of ligand-type on the f-f MCD fine structure features. Theoretical calculations were conducted to determine the Laporte forbidden f-f transitions and their MCD intensity experimentally observed in the NIR spectra of the U(v) hexahalide complexes, via the inclusion of vibronic coupling, to better understand the underlying spectral fine structure features for these complexes. These spectra and simulations provide an important platform for the application of MCD spectroscopy to this widely studied class of U(v) complexes and identify areas for continued theoretical development.
