Liu Tianhao, Wang Ying, Zhou Jin, Li Mengyang, Yue Jinquan
Key Laboratory of Bio-based Material Science & Technology, Northeast Forestry University, Ministry of Education, Harbin 150040, China.
Polymers (Basel). 2021 Apr 21;13(9):1349. doi: 10.3390/polym13091349.
In this study, molded fiber products (MFPs) were prepared from lignin compounded with Lewis acid-modified fibers using enzymatic hydrolysis lignin (EHL) as a bio-phenol. The fibers were modified and compounded entirely through hot-pressing. To improve the reactivity of enzymatic lignin, hydroxylated enzymatic hydrolysis lignin (HEHL) was prepared by hydroxylation modification of purified EHL with hydrogen peroxide (HO) and ferrous hydroxide (Fe(OH)). HEHL was mixed uniformly with Lewis acid-modified fibers on a pressure machine and modified during the molding process. The purpose of Lewis acid degradation of hemicellulose-converted furfural with HEHL was to generate a resin structure to improve the mechanical properties of a MFPs. The microstructure of the MFP was shown to be generated by resin structure, and it was demonstrated that HEHL was compounded on Lewis acid-modified fibers during the molding process. The thermal stability of the MFP with composite HEHL did not change significantly owing to the addition of lignin and had higher tensile strength (46.28 MPa) and flexural strength (65.26 MPa) compared to uncompounded and modified MFP. The results of this study are expected to promote the application of high lignin content fibers in molded fibers.
在本研究中,以酶解木质素(EHL)作为生物酚,将其与路易斯酸改性纤维复合制备模塑纤维产品(MFP)。纤维的改性和复合完全通过热压完成。为提高酶解木质素的反应活性,用过氧化氢(HO)和氢氧化亚铁(Fe(OH))对纯化后的EHL进行羟基化改性制备了羟基化酶解木质素(HEHL)。将HEHL在压力机上与路易斯酸改性纤维均匀混合,并在成型过程中进行改性。用HEHL使半纤维素转化的糠醛进行路易斯酸降解的目的是生成一种树脂结构,以改善MFP的机械性能。结果表明,MFP的微观结构由树脂结构生成,并且证明了在成型过程中HEHL复合在了路易斯酸改性纤维上。由于添加了木质素,复合HEHL的MFP的热稳定性没有显著变化,并且与未复合和未改性的MFP相比,具有更高的拉伸强度(46.28 MPa)和弯曲强度(65.26 MPa)。本研究结果有望促进高木质素含量纤维在模塑纤维中的应用。