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新型溶胶-凝胶杂化菊粉-正硅酸乙酯吸附剂的制备与表征

Preparation and Characterization of New Sol-Gel Hybrid Inulin-TEOS Adsorbent.

作者信息

Mohd Yusop Hartina, Mohd Ismail Annur Isma Husna, Wan Ismail Wan Norfazilah

机构信息

Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak, Gambang, Kuantan 26300, Pahang, Malaysia.

出版信息

Polymers (Basel). 2021 Apr 15;13(8):1295. doi: 10.3390/polym13081295.

DOI:10.3390/polym13081295
PMID:33921052
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8071460/
Abstract

A new biopolymer-silica hybrid material consisting of inulin and tetraethoxysilane (TEOS) for use as an adsorbent was successfully synthesized via the sol-gel method in acidic conditions. The hydrolysis and condensation processes were attained in water/ethanol solution. Three molar ratios of inulin:TEOS (1:1, 1:2, and 2:1) were prepared and dried at various temperatures (50, 60, and 70 °C). The optimized molar ratio of 2:1 with a drying temperature of 70 °C was found to obtain the best morphology and characteristics for absorbent properties. Fourier transform infrared spectroscopy (FTIR) analysis showed a strong interaction between inulin and TEOS, which was also observed using energy dispersive X-ray spectroscopy (EDX). Field emission scanning electron microscopy (FESEM) images revealed the presence of nanoparticles on the rough surface of the hybrid sol-gel. X-ray diffractometer (XRD) analysis showed the amorphous state of the silica network where the inulin existed as an anhydrous crystalline phase. Brunauer-Emmet-Teller (BET) analysis confirmed that the composite was mesoporous, with 17.69 m/g surface area and 34.06 Å pore size. According to thermogravimetric analysis (TGA) results, the hybrid inulin-TEOS adsorbent was thermally stable under a temperature of 200 °C.

摘要

一种由菊粉和四乙氧基硅烷（TEOS）组成的新型生物聚合物 - 二氧化硅杂化材料被成功地通过溶胶 - 凝胶法在酸性条件下合成用作吸附剂。水解和缩合过程在水/乙醇溶液中进行。制备了三种菊粉与TEOS的摩尔比（1:1、1:2和2:1）并在不同温度（50、60和70°C）下干燥。发现摩尔比为2:1且干燥温度为70°C时可获得具有最佳形态和吸附特性的材料。傅里叶变换红外光谱（FTIR）分析表明菊粉和TEOS之间存在强相互作用，能量色散X射线光谱（EDX）分析也观察到了这种相互作用。场发射扫描电子显微镜（FESEM）图像显示在杂化溶胶 - 凝胶的粗糙表面上存在纳米颗粒。X射线衍射仪（XRD）分析表明二氧化硅网络为非晶态，其中菊粉以无水结晶相存在。布鲁诺尔 - 埃米特 - 泰勒（BET）分析证实该复合材料为介孔材料，表面积为17.69 m/g，孔径为34.06 Å。根据热重分析（TGA）结果，菊粉 - TEOS杂化吸附剂在200°C以下具有热稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/b2ed8c70dd0f/polymers-13-01295-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/6df271ea4e8c/polymers-13-01295-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/a54d900e3bfb/polymers-13-01295-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/6a0c03737a33/polymers-13-01295-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/544f31677999/polymers-13-01295-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/803f75adc280/polymers-13-01295-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/93511173298b/polymers-13-01295-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/980a15a24dd4/polymers-13-01295-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/20c24baff740/polymers-13-01295-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/7176e889ce94/polymers-13-01295-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/b2ed8c70dd0f/polymers-13-01295-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/6df271ea4e8c/polymers-13-01295-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/a54d900e3bfb/polymers-13-01295-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/6a0c03737a33/polymers-13-01295-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/544f31677999/polymers-13-01295-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/803f75adc280/polymers-13-01295-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/93511173298b/polymers-13-01295-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/980a15a24dd4/polymers-13-01295-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/20c24baff740/polymers-13-01295-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/7176e889ce94/polymers-13-01295-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c7c1/8071460/b2ed8c70dd0f/polymers-13-01295-g009.jpg

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本文引用的文献

1
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Nanoscale Adv. 2018 Sep 26;1(1):389-394. doi: 10.1039/c8na00044a. eCollection 2019 Jan 15.
2
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Int J Biol Macromol. 2020 May 1;150:1072-1083. doi: 10.1016/j.ijbiomac.2019.10.113. Epub 2019 Nov 15.
3
Polyamine-co-2, 6-diaminopyridine covalently bonded on chitosan for the adsorptive removal of Hg(II) ions from aqueous solution.
壳聚糖上共价键合的多胺-2,6-二氨基吡啶用于从水溶液中吸附去除 Hg(II)离子。
Int J Biol Macromol. 2019 Jun 1;130:853-862. doi: 10.1016/j.ijbiomac.2019.03.007. Epub 2019 Mar 3.
4
"Traditional" Sol-Gel Chemistry as a Powerful Tool for the Preparation of Supported Metal and Metal Oxide Catalysts.“传统”溶胶-凝胶化学作为制备负载型金属和金属氧化物催化剂的有力工具。
Materials (Basel). 2019 Feb 23;12(4):668. doi: 10.3390/ma12040668.
5
Synthesis and characterization of biopolymer based hybrid hydrogel nanocomposite and study of their electrochemical efficacy.基于生物聚合物的杂化水凝胶纳米复合材料的合成与表征及其电化学性能研究。
Int J Biol Macromol. 2019 Feb 15;123:228-238. doi: 10.1016/j.ijbiomac.2018.11.010. Epub 2018 Nov 7.
6
Overview of wastewater treatment methods with special focus on biopolymer chitin-chitosan.废水处理方法概述，特别关注生物聚合物几丁质-壳聚糖。
Int J Biol Macromol. 2019 Jan;121:1086-1100. doi: 10.1016/j.ijbiomac.2018.10.089. Epub 2018 Oct 18.
7
Evaluation of Inulin Replacing Chitosan in a Polyurethane/Polysaccharide Material for Pb Removal.评估菊粉替代壳聚糖在用于去除 Pb 的聚氨酯/多糖材料中的作用。
Molecules. 2017 Nov 29;22(12):2093. doi: 10.3390/molecules22122093.
8
Synthesis, Structural, and Adsorption Properties and Thermal Stability of Nanohydroxyapatite/Polysaccharide Composites.纳米羟基磷灰石/多糖复合材料的合成、结构、吸附性能及热稳定性
Nanoscale Res Lett. 2017 Dec;12(1):155. doi: 10.1186/s11671-017-1911-5. Epub 2017 Feb 27.
9
Liquid phase adsorption behavior of inulin-type fructan onto activated charcoal.菊粉型果聚糖在活性炭上的液相吸附行为。
Carbohydr Polym. 2015 May 20;122:237-42. doi: 10.1016/j.carbpol.2015.01.019. Epub 2015 Jan 15.
10
Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: a review.壳聚糖及其衍生物在去除水和废水中染料的应用：综述。
Carbohydr Polym. 2014 Nov 26;113:115-30. doi: 10.1016/j.carbpol.2014.07.007. Epub 2014 Jul 12.