Burgada Francisco, Fages Eduardo, Quiles-Carrillo Luis, Lascano Diego, Ivorra-Martinez Juan, Arrieta Marina P, Fenollar Octavio
Textile Research Institute (AITEX), Plaza Emilio Sala 1, 03801 Alcoy, Spain.
Technological Institute of Materials (ITM), Universitat Politècnica de València (UPV), Plaza Ferrándiz y Carbonell 1, 03801 Alcoy, Spain.
Polymers (Basel). 2021 Apr 12;13(8):1248. doi: 10.3390/polym13081248.
This research reports the manufacturing and characterization of green composites made from recycled polypropylene obtained from the remnants of polypropylene non-woven fabrics used in the textile industry and further reinforced with short hemp fibers (SHFs). To improve the interaction of the reinforcing fibers with the recycled polymeric matrix, two types of compatibilizing agents (maleic anhydride grafted, PP-g-MA, and maleinized linseed oil, MLO) were added during melt-processing, the percentage of which had to remain constant concerning the amount of fiber loading to ensure complete reactivity. Standardized test specimens were obtained by injection molding. The composites were characterized by mechanical (tensile, impact, and hardness), thermal (DSC, TGA), thermomechanical, FTIR, and FESEM microscopy tests. In addition, color and water uptake properties were also analyzed. The results show that the addition of PP-g-MA to rPP was satisfactory, thus improving the fiber-matrix interaction, resulting in a marked reinforcing effect of the hemp fibers in the recycled PP matrix, which can be reflected in the increased stiffness of the samples. In parallel to the compatibilizing effect, a plasticizing effect was obtained by incorporating MLO, causing a decrease in the glass transition temperature of the composites by approximately 6 °C and an increase in ductility compared to the unfilled recycled polypropylene samples.
本研究报告了由纺织工业中聚丙烯无纺布残余物制得的回收聚丙烯制成的绿色复合材料的制造及表征,并进一步用短麻纤维(SHF)进行增强。为改善增强纤维与回收聚合物基体之间的相互作用,在熔融加工过程中添加了两种增容剂(马来酸酐接枝聚丙烯,PP-g-MA,以及马来化亚麻籽油,MLO),其百分比相对于纤维负载量必须保持恒定,以确保完全反应。通过注塑成型获得标准化测试样品。通过机械性能(拉伸、冲击和硬度)、热性能(DSC、TGA)、热机械性能、FTIR和FESEM显微镜测试对复合材料进行表征。此外,还分析了颜色和吸水性。结果表明,向回收聚丙烯中添加PP-g-MA效果良好,从而改善了纤维与基体之间的相互作用,使麻纤维在回收聚丙烯基体中产生显著的增强效果,这可体现在样品刚度的增加上。与增容效果同时,通过加入MLO获得了增塑效果,使复合材料的玻璃化转变温度降低约6℃,与未填充的回收聚丙烯样品相比,延展性增加。