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高炉矿渣碱激发砂浆的流变学及新拌状态性能

Rheological and the Fresh State Properties of Alkali-Activated Mortars by Blast Furnace Slag.

作者信息

Marvila Markssuel Teixeira, Azevedo Afonso Rangel Garcez de, Matos Paulo Ricardo de, Monteiro Sérgio Neves, Vieira Carlos Maurício Fontes

机构信息

LAMAV-Advanced Materials Laboratory, UENF-State University of the Northern Rio de Janeiro, Av. Alberto Lamego, 2000, 28013-602 Campos dos Goytacazes, Brazil.

LECIV-Civil Engineering Laboratory, UENF-State University of the Northern Rio de Janeiro, Av. Alberto Lamego, 2000, 28013-602 Campos dos Goytacazes, Brazil.

出版信息

Materials (Basel). 2021 Apr 20;14(8):2069. doi: 10.3390/ma14082069.

Abstract

The fresh and rheological properties of alkali mortars activated by blast furnace slag (BFS) were investigated. Consistency tests, squeeze flow, dropping ball, mass density in the hardened state, incorporated air, and water retention were performed. Mortars were produced with the ratio 1:2:0.45 (binder:sand:water), using not only ordinary Portland cement for control but also BFS, varying the sodium content of the activated alkali mortars from 2.5 to 15%. The results obtained permitted understanding that mortars containing 2.5 to 7.5% sodium present a rheological behavior similar to cementitious mortars by the Bingham model. In turn, the activated alkali mortars containing 10 to 15% sodium showed a very significant change in the properties of dynamic viscosity, which is associated with a change in the type of model, starting to behave similar to the Herschel-Bulkley model. Evaluating the properties of incorporated air and water retention, it appears that mortars containing 12.5% and 15% sodium do not have compatible properties, which is related to the occupation of sodium ions in the interstices of the material. Thus, it is concluded that the techniques used were consistent in the rheological characterization of activated alkali mortars.

摘要

研究了高炉矿渣(BFS)激发的碱砂浆的新拌性能和流变性能。进行了稠度试验、挤压流动试验、落球试验、硬化状态下的质量密度、含气量和保水性试验。砂浆按1:2:0.45(胶凝材料:砂:水)的比例制备,不仅使用普通硅酸盐水泥作为对照,还使用BFS,将激发碱砂浆的钠含量从2.5%变化到15%。所得结果表明,钠含量为2.5%至7.5%的砂浆通过宾汉模型呈现出与水泥基砂浆相似的流变行为。反过来,钠含量为10%至15%的激发碱砂浆在动态粘度性能上表现出非常显著的变化,这与模型类型的变化有关,开始表现得类似于赫谢尔-巴克利模型。评估含气量和保水性的性能,发现钠含量为12.5%和15%的砂浆不具有相容的性能,这与钠离子在材料孔隙中的占据有关。因此,得出结论,所采用的技术在激发碱砂浆的流变特性表征方面是一致的。

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