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基于响应面模型揭示的碱激发材料配比因子及相互作用关系

Proportioning Factors of Alkali-Activated Materials and Interaction Relationship Revealed by Response Surface Modeling.

作者信息

Zhao Jun, Wang Aiguo, Lyu Bangcheng, Liu Kaiwei, Chu Yingjie, Ma Rui, Xu Haiyan, Jing Yan, Sun Daosheng

机构信息

Anhui Province Engineering Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230601, China.

School of Materials Science & Engineering, Southeast University, Nanjing 211189, China.

出版信息

Materials (Basel). 2023 Mar 1;16(5):2042. doi: 10.3390/ma16052042.

Abstract

Alkali-activated fly-ash-slag blending materials (AA-FASMs) are gradually being studied and applied more because of their good performance. There are many factors affecting the alkali-activated system, and the effect of single-factor variation on the performance of AA-FASM has been mostly reported; however, there is a lack of unified understanding of the mechanical properties and microstructure of AA-FASM under curing conditions and multiple-factor interaction. Therefore, this study investigated the compressive strength development and reaction products of alkali-activated AA-FASM under three curing conditions including seal (S), dry (D) and water saturation (W). Based on the response surface model, the relationship between the interaction of slag content (), activator modulus () and activator dosage () on its strength was established. The results showed that the maximum compressive strength of AA-FASM after 28 days of sealed curing was about 59 MPa, while the strengths of dry- and water-saturation-cured specimens decreased by 9.8% and 13.7%, respectively. The seal-cured samples also had the smallest mass change rate and linear shrinkage and the most compact pore structure. Due to the adverse effects from a too-high or too-low modulus and dosage of the activators, the shapes of upward convex, slope and inclined convex were under the interaction of /, / and /, respectively. The correlation coefficient > 0.95 and -value < 0.05 indicated that the proposed model could be used to predict strength development given the complex factors. Optimal proportioning and curing conditions were found to be = 50%, = 1.4, = 50% and sealed curing.

摘要

碱激发粉煤灰-矿渣混合材料(AA-FASMs)因其良好的性能而逐渐受到更多的研究和应用。影响碱激发体系的因素众多,单因素变化对AA-FASM性能的影响已有较多报道;然而,对于AA-FASM在养护条件和多因素相互作用下的力学性能和微观结构缺乏统一认识。因此,本研究考察了在密封(S)、干燥(D)和饱水(W)三种养护条件下碱激发AA-FASM的抗压强度发展及反应产物。基于响应面模型,建立了矿渣含量()、激发剂模量()和激发剂用量()相互作用对其强度的关系。结果表明,密封养护28天后AA-FASM的最大抗压强度约为59MPa,而干燥养护和饱水养护试件的强度分别降低了9.8%和13.7%。密封养护的样品质量变化率和线性收缩也最小,孔隙结构最致密。由于激发剂模量和用量过高或过低的不利影响,在/、/和/相互作用下分别呈现上凸、斜率和斜凸形状。相关系数>0.95且-值<0.05表明所提出的模型可用于预测复杂因素下的强度发展。发现最佳配合比和养护条件为=50%,=1.4,=50%和密封养护。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6c79/10003878/c26dbd097de8/materials-16-02042-g001.jpg

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