Department of Physics, School of Engineering, São Paulo State University (UNESP), Guaratinguetá, Sao Paulo 12516-410, Brazil.
São Carlos Institute of Physics, University of São Paulo, 369, São Carlos, Sao Paulo 13560-970, Brazil.
Molecules. 2021 Apr 13;26(8):2236. doi: 10.3390/molecules26082236.
Over the last two decades, oxide nanostructures have been continuously evaluated and used in many technological applications. The advancement of the controlled synthesis approach to design desired morphology is a fundamental key to the discipline of material science and nanotechnology. These nanostructures can be prepared via different physical and chemical methods; however, a green and ecofriendly synthesis approach is a promising way to produce these nanostructures with desired properties with less risk of hazardous chemicals. In this regard, ZnO and TiO nanostructures are prominent candidates for various applications. Moreover, they are more efficient, non-toxic, and cost-effective. This review mainly focuses on the recent state-of-the-art advancements in the green synthesis approach for ZnO and TiO nanostructures and their applications. The first section summarizes the green synthesis approach to synthesize ZnO and TiO nanostructures via different routes such as solvothermal, hydrothermal, co-precipitation, and sol-gel using biological systems that are based on the principles of green chemistry. The second section demonstrates the application of ZnO and TiO nanostructures. The review also discusses the problems and future perspectives of green synthesis methods and the related issues posed and overlooked by the scientific community on the green approach to nanostructure oxides.
在过去的二十年中,氧化物纳米结构不断得到评估,并在许多技术应用中得到使用。控制合成方法的进步,以设计所需的形态,是材料科学和纳米技术这一学科的基本关键。这些纳米结构可以通过不同的物理和化学方法制备;然而,绿色环保的合成方法是一种很有前途的方法,可以用较少的危险化学品生产具有所需性能的这些纳米结构。在这方面,氧化锌 (ZnO) 和二氧化钛 (TiO) 纳米结构是各种应用的突出候选材料。此外,它们更高效、无毒且具有成本效益。本综述主要关注绿色合成 ZnO 和 TiO 纳米结构及其应用的最新研究进展。第一部分总结了通过不同途径(如溶剂热法、水热法、共沉淀法和溶胶-凝胶法)使用基于绿色化学原理的生物体系合成 ZnO 和 TiO 纳米结构的绿色合成方法。第二部分展示了 ZnO 和 TiO 纳米结构的应用。本综述还讨论了绿色合成方法的问题和未来展望,以及科学界对绿色方法制备纳米结构氧化物所提出和忽视的相关问题。