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苯并恶嗪树脂的加速聚合和低温聚合综述：可加成聚合的可持续聚合物

Review on the Accelerated and Low-Temperature Polymerization of Benzoxazine Resins: Addition Polymerizable Sustainable Polymers.

作者信息

Lochab Bimlesh, Monisha Monisha, Amarnath Nagarjuna, Sharma Pratibha, Mukherjee Sourav, Ishida Hatsuo

机构信息

Materials Chemistry Laboratory, Department of Chemistry, School of Natural Sciences, Shiv Nadar University, Gautam Buddha Nagar, Uttar Pradesh 201314, India.

Department of Polymer Science and Engineering, Indian Institute of Technology, Hauz Khas, New Delhi 110016, India.

出版信息

Polymers (Basel). 2021 Apr 13;13(8):1260. doi: 10.3390/polym13081260.

DOI:10.3390/polym13081260
PMID:33924552
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8069336/
Abstract

Due to their outstanding and versatile properties, polybenzoxazines have quickly occupied a great niche of applications. Developing the ability to polymerize benzoxazine resin at lower temperatures than the current capability is essential in taking advantage of these exceptional properties and remains to be most challenging subject in the field. The current review is classified into several parts to achieve this goal. In this review, fundamentals on the synthesis and evolution of structure, which led to classification of PBz in different generations, are discussed. Classifications of PBzs are defined depending on building block as well as how structure is evolved and property obtained. Progress on the utility of biobased feedstocks from various bio-/waste-mass is also discussed and compared, wherever possible. The second part of review discusses the probable polymerization mechanism proposed for the ring-opening reactions. This is complementary to the third section, where the effect of catalysts/initiators has on triggering polymerization at low temperature is discussed extensively. The role of additional functionalities in influencing the temperature of polymerization is also discussed. There has been a shift in paradigm beyond the lowering of ring-opening polymerization (ROP) temperature and other areas of interest, such as adaptation of molecular functionality with simultaneous improvement of properties.

摘要

由于其优异且多样的性能，聚苯并恶嗪已迅速占据了大量应用领域。开发在比当前能力更低的温度下聚合苯并恶嗪树脂的能力，对于利用这些优异性能至关重要，并且仍然是该领域最具挑战性的课题。为实现这一目标，本综述分为几个部分。在本综述中，讨论了导致聚苯并恶嗪分为不同代的结构合成与演变的基本原理。聚苯并恶嗪的分类取决于构建单元以及结构如何演变和性能如何获得。还尽可能讨论并比较了来自各种生物/废物原料的生物基原料的应用进展。综述的第二部分讨论了为开环反应提出的可能的聚合机理。这与第三部分互补，在第三部分中广泛讨论了催化剂/引发剂对低温引发聚合的影响。还讨论了其他官能团在影响聚合温度方面的作用。除了降低开环聚合（ROP）温度之外，在范式上已经发生了转变，还有其他感兴趣的领域，例如分子官能团的适配以及性能的同时改善。

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Gels. 2023 Oct 14;9(10):819. doi: 10.3390/gels9100819.
6
Catalyzing Benzoxazine Polymerization with Titanium-Containing POSS to Reduce the Curing Temperature and Improve Thermal Stability.用含钛倍半硅氧烷催化苯并恶嗪聚合以降低固化温度并提高热稳定性
Molecules. 2023 Jul 17;28(14):5450. doi: 10.3390/molecules28145450.
7
Plasmonic visible-near infrared photothermal activation of olefin metathesis enabling photoresponsive materials.等离子体可见-近红外光热激活烯烃复分解反应，实现光响应材料。
Nat Chem. 2023 Apr;15(4):475-482. doi: 10.1038/s41557-022-01124-7. Epub 2023 Jan 26.
8
Metal Ion-Catalyzed Low-Temperature Curing of Urushiol-Based Polybenzoxazine.金属离子催化漆酚基聚苯并恶嗪的低温固化
Front Chem. 2022 Apr 28;10:879605. doi: 10.3389/fchem.2022.879605. eCollection 2022.
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Adhesive Films Based on Benzoxazine Resins and the Photoreactive Epoxyacrylate Copolymer.基于苯并恶嗪树脂和光反应性环氧丙烯酸酯共聚物的胶粘剂薄膜。
Materials (Basel). 2022 Mar 1;15(5):1839. doi: 10.3390/ma15051839.
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The Influence of Substituents in Phosphazene Catalyst-Flame Retardant on the Thermochemistry of Benzoxazine Curing.
Polymers (Basel). 2021 Sep 15;13(18):3111. doi: 10.3390/polym13183111.
研究羟基对聚苯并恶嗪热性能的影响：采用分子设计和蒙特卡罗模拟
RSC Adv. 2018 May 18;8(32):18038-18050. doi: 10.1039/c8ra02033g. eCollection 2018 May 14.
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Curing kinetics of phenolphthalein based polyphosphazene towards thermal stability and flame retardancy of polybenzoxazine.基于酚酞的聚磷腈对聚苯并恶嗪热稳定性和阻燃性的固化动力学
RSC Adv. 2019 Oct 4;9(54):31583-31593. doi: 10.1039/c9ra06857k. eCollection 2019 Oct 1.
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Synthesis and thermally induced structural transformation of phthalimide and nitrile-functionalized benzoxazine: toward smart -benzoxazine chemistry for low flammability thermosets.邻苯二甲酰亚胺和腈基官能化苯并恶嗪的合成及热致结构转变：迈向用于低易燃性热固性材料的智能苯并恶嗪化学
RSC Adv. 2019 Jan 11;9(3):1526-1535. doi: 10.1039/c8ra10009h. eCollection 2019 Jan 9.
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Antibacterial performance of fully biobased chitosan-grafted-polybenzoxazine films: Elaboration and properties of released material.全生物基壳聚糖接枝聚苯并恶嗪膜的抗菌性能：释放材料的制备与性能。
Carbohydr Polym. 2021 Feb 15;254:117296. doi: 10.1016/j.carbpol.2020.117296. Epub 2020 Oct 24.
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Design and Effects of the Cinnamic Acids Chemical Structures as Organocatalyst on the Polymerization of Benzoxazines.肉桂酸化学结构作为有机催化剂对苯并恶嗪聚合反应的设计及影响
Polymers (Basel). 2020 Jul 9;12(7):1527. doi: 10.3390/polym12071527.
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Cerium Salts: An Efficient Curing Catalyst for Benzoxazine Based Coatings.铈盐：一种用于苯并恶嗪基涂料的高效固化催化剂。
Polymers (Basel). 2020 Feb 11;12(2):415. doi: 10.3390/polym12020415.
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Highly Crosslinked Polybenzoxazines from Monobenzoxazines: The Effect of Meta-Substitution in the Phenol Ring.由单苯并恶嗪制得的高度交联聚苯并恶嗪：酚环间位取代的影响
Polymers (Basel). 2020 Jan 21;12(2):254. doi: 10.3390/polym12020254.
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Easily Processable Thermosets with Outstanding Performance via Smart Twisted Small-Molecule Benzoxazines.通过智能扭曲小分子苯并恶嗪实现易加工的高性能热固性塑料。
Macromol Rapid Commun. 2020 Mar;41(5):e1900625. doi: 10.1002/marc.201900625. Epub 2020 Jan 20.