Wang Fang, Wang Bowen, Zhang Xuhui, Lu Mengdi, Zhang Yang, Sun Changsen, Peng Wei
School of Optoelectronic Engineering and Instrument Science, Dalian University of Technology, Dalian 116024, China.
School of Physics, Dalian University of Technology, Dalian 116024, China.
Nanomaterials (Basel). 2021 Apr 27;11(5):1134. doi: 10.3390/nano11051134.
A high performance humidity sensor using tilted fiber Bragg grating (TFBG) and functional graphene oxide (GO)/multi-walled carbon nanotubes (MWCNTs) hybrid nano-materials was proposed. The humidity-sensitive material with three-dimensional (3D) structure was synthesized by the MWCNTs and GOs. Comparing with traditional two dimensional (2D) GOs film, water molecules could be absorbed effectively due to the larger ripples and more holes in GO/MWCNTs layers. The water molecule will fill the entire space in the 3D structure instead of air, which further enhances the absorption efficiency of the hybrid nanomaterial. TFBG as a compact and robust surrounding complex dielectric constant sensing platform was utilized. The mode coupling coefficient or the amplitude of TFBG cladding mode will vary sharply with the imaginary part of permittivity of the hybrid nanomaterial, realizing the high performance RH sensing. In the experiments, we successfully demonstrated that this 3D structural nanomaterial composed by the MWCNTs and GOs has significant advantages for expanding the range of humidity detection (range from 30% to 90%) and enhancing the detection sensitivity (0.377 dB/% RH is twice more than humidity sensor with 2D GO film). The TFBG-based RH sensor also exhibits good repeatability and stability. Our proposed humidity sensor has potential application in environmental and healthy monitoring fields.
提出了一种使用倾斜光纤布拉格光栅(TFBG)和功能化氧化石墨烯(GO)/多壁碳纳米管(MWCNT)混合纳米材料的高性能湿度传感器。由MWCNT和GO合成了具有三维(3D)结构的湿度敏感材料。与传统的二维(2D)GO薄膜相比,由于GO/MWCNT层中更大的波纹和更多的孔洞,水分子能够被有效吸收。水分子将填充3D结构中的整个空间而非空气,这进一步提高了混合纳米材料的吸收效率。利用TFBG作为紧凑且坚固的周围复介电常数传感平台。TFBG包层模式的模式耦合系数或幅度将随混合纳米材料介电常数的虚部急剧变化,实现高性能的相对湿度(RH)传感。在实验中,我们成功证明了这种由MWCNT和GO组成的3D结构纳米材料在扩展湿度检测范围(30%至90%)和提高检测灵敏度(0.377 dB/%RH,比具有2D GO薄膜的湿度传感器高出两倍)方面具有显著优势。基于TFBG的RH传感器还表现出良好的重复性和稳定性。我们提出的湿度传感器在环境和健康监测领域具有潜在应用。