College of Biological and Environmental Engineering, Zhejiang Shuren University, Hangzhou, 310015, China; Department of Environmental Engineering, Wuchang University of Technology, Wuhan, 430223, China.
Department of Environmental Engineering, Wuchang University of Technology, Wuhan, 430223, China.
Talanta. 2021 Aug 1;230:122299. doi: 10.1016/j.talanta.2021.122299. Epub 2021 Mar 20.
Colorimetric sensors for the rapid detection of numerous analytes have been widely applied in many fields such as biomedicine, food industry and environmental science due to their highly sensitive and selective response, easy operation and visual identification by naked eyes. In this review, the recent progress of the colorimetric sensors based on the magnetic nanomaterials with unique nanozymes-like catalytic activity (magnetic nanozyme) and their colorimetric sensing applications are presented. Emerging magnetic nanozyme-based colorimetric sensors, such as metal oxide/sulfides-based, metal-based, carbon-based, and aptamer-conjugated magnetic nanomaterials, offer many desirable features for target analytes detection. And due to the unique nanoscale physical-chemical properties, magnetic nanozymes have been used to mimic the catalytic activity of natural enzymes such as peroxidases, oxidases and catalases. This review also highlights the catalytic mechanisms of enzyme-like reactions, and promising colorimetric sensing system for the detection of chemical compounds like HO, pesticide, ascorbic acid, dopamine, tetracyclines, perfluorooctane sulfonate, phenolic compounds, heavy metal ion and sulfite have been deeply discussed. In addition, the remaining challenges and future directions in utilizing magnetic nanozyme for colorimetric sensors are addressed.
基于具有独特纳米酶样催化活性(磁性纳米酶)的磁性纳米材料的比色传感器及其比色传感应用的最新进展。新兴的基于磁性纳米酶的比色传感器,如金属氧化物/硫化物基、金属基、碳基和适配体偶联磁性纳米材料,为目标分析物的检测提供了许多理想的特性。由于独特的纳米尺度物理化学性质,磁性纳米酶已被用于模拟过氧化物酶、氧化酶和过氧化氢酶等天然酶的催化活性。本文还重点介绍了类酶反应的催化机制,以及用于检测 HO、农药、抗坏血酸、多巴胺、四环素、全氟辛烷磺酸、酚类化合物、重金属离子和亚硫酸盐等化合物的有前途的比色传感系统。此外,还讨论了利用磁性纳米酶用于比色传感器的剩余挑战和未来方向。
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