连锁热力学的规范表述。
Canonical formulation of linkage thermodynamics.
作者信息
Di Cera E, Gill S J, Wyman J
机构信息
Department of Chemistry and Biochemistry, University of Colorado, Boulder 80309-0215.
出版信息
Proc Natl Acad Sci U S A. 1988 Jul;85(14):5077-81. doi: 10.1073/pnas.85.14.5077.
Abstract
The canonical structure of the group of thermodynamic potentials obtained from the energy of a physico-chemical system removes any possible distinction between physical and chemical binding phenomena. Transformations of these potentials by means of Jacobians give linkage relations for equilibrium thermodynamics. Linkage matrices are introduced to explore the functional properties of a biological macromolecule. They provide a quantitative basis for a broader approach and understanding of generalized binding phenomena.
摘要
从物理化学系统的能量得出的热力学势群的正则结构消除了物理和化学结合现象之间任何可能的区别。通过雅可比行列式对这些势进行变换，可得到平衡热力学的连锁关系。引入连锁矩阵以探索生物大分子的功能特性。它们为更广泛地研究和理解广义结合现象提供了定量基础。
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