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使用盐包水电解质的高温超级电容器:100°C以上的稳定性

High temperature supercapacitors using water-in-salt electrolytes: stability above 100 °C.

作者信息

Le Fevre Lewis W, Ejigu Andinet, Todd Rebecca, Forsyth Andrew J, Dryfe Robert A W

机构信息

Department of Electrical and Electronic Engineering, The University of Manchester, Manchester, M13 9PL, UK and Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK.

Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK.

出版信息

Chem Commun (Camb). 2021 May 27;57(43):5294-5297. doi: 10.1039/d1cc01087e.

DOI:10.1039/d1cc01087e
PMID:33942833
Abstract

The high temperature performance of water-in-salt electrolytes was investigated using a carbon-based electrode with commercial cell components. Supercapacitors using 21 m Li bis(trifluoromethylsulphonyl)imide (TFSI) and 21 m LiTFSI + 7 m Li trifluoromethanesulphonyl electrolytes are shown to operate at a voltage of 2 V at 100 °C and 120 °C, respectively, with gravimetric capacitances exceeding 100 F g-1.

摘要

使用具有商业电池组件的碳基电极研究了盐包水电解质的高温性能。结果表明,使用21 m Li双(三氟甲基磺酰)亚胺(TFSI)和21 m LiTFSI + 7 m 三氟甲磺酸锂电解质的超级电容器分别在100°C和120°C下以2 V的电压运行,其重量电容超过100 F g-1。

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