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考虑硫酸盐侵蚀的混凝土材料力学性能及损伤演化

Mechanical Properties and Damage Evolution of Concrete Materials Considering Sulfate Attack.

作者信息

Wu Qianyun, Ma Qinyong, Huang Xianwen

机构信息

School of Civil Engineering and Architecture, Anhui University of Science and Technology, Huainan 232001, China.

Engineering Research Center of Underground Mine Construction, Ministry of Education, Anhui University of Science and Technology, Huainan 232001, China.

出版信息

Materials (Basel). 2021 Apr 30;14(9):2343. doi: 10.3390/ma14092343.

Abstract

In order to study the durability of concrete materials subjected to sulfate attack, in a sulfate attack environment, a series of concrete tests considering different fly ash contents and erosion times were conducted. The mechanical properties and the micro-structure of concrete under sulfate attack were studied based on the following: uniaxial compressive strength test, split tensile test, ultrasonic impulse method, scanning electron microscopy (SEM) and X-ray diffraction (XRD). The mechanical properties were compressive strength, splitting tensile strength, and relative dynamic elastic modulus, respectively. Additionally, according to the damage mechanical theory, experimental results and micro-structure analysis, the damage evolution process of concrete under a sulfate attack environment were studied in detail. Finally, according to the sulfate attack time and fly ash content, a damage model of the sulfate attack of the binary surface was established. The specific results are as follows: under the action of sulfate attack, the change law of the rate of mass change, relative dynamic modulus of elasticity, corrosion resistance coefficient of compressive strength, and the corrosion resistance coefficient of the splitting tensile strength of concrete all increase first and then decrease. Under the same erosion time, concrete mixed with 10% fly ash content has the best sulfate resistance. Through data regression, the damage evolution equation of the sulfate attack was developed and there is an exponential function relationship among the different damage variables. The binary curved surface regression effect of the concrete damage and the erosion time and the amount of fly ash is significant, which can predict deterioration of concrete damage under sulfate attack. During the erosion time, the combined expansion of ettringite and gypsum caused micro cracks. With an increase of corrosion time, micro cracks developed and their numbers increased.

摘要

为研究混凝土材料在硫酸盐侵蚀环境下的耐久性,开展了一系列考虑不同粉煤灰掺量和侵蚀时间的混凝土试验。基于以下方面研究了硫酸盐侵蚀作用下混凝土的力学性能和微观结构:单轴抗压强度试验、劈裂抗拉试验、超声脉冲法、扫描电子显微镜(SEM)和X射线衍射(XRD)。力学性能分别为抗压强度、劈裂抗拉强度和相对动弹模量。此外,根据损伤力学理论、试验结果和微观结构分析,详细研究了硫酸盐侵蚀环境下混凝土的损伤演化过程。最后,根据硫酸盐侵蚀时间和粉煤灰掺量,建立了二元表面硫酸盐侵蚀损伤模型。具体结果如下:在硫酸盐侵蚀作用下,混凝土质量变化率、相对动弹模量、抗压强度抗蚀系数和劈裂抗拉强度抗蚀系数的变化规律均为先增大后减小。在相同侵蚀时间下,粉煤灰掺量为10%的混凝土抗硫酸盐性能最佳。通过数据回归,得到了硫酸盐侵蚀损伤演化方程,不同损伤变量之间存在指数函数关系。混凝土损伤与侵蚀时间和粉煤灰掺量的二元曲面回归效果显著,可预测硫酸盐侵蚀作用下混凝土损伤的劣化情况。在侵蚀时间内,钙矾石和石膏的联合膨胀导致微裂纹产生。随着侵蚀时间的增加,微裂纹扩展且数量增多。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b239/8124883/b8079d8d2785/materials-14-02343-g001.jpg

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