Stimuli-Responsive Electrospun Piezoelectric Mats of Ethylene--vinyl Acetate-Millable Polyurethane-Nanohydroxyapatite Composites.

Piezoelectric materials have gained interest among materials scientists as body motion sensors and energy harvesters on account of their fast responsiveness and substantial output signals. In this work, piezoelectric polymer mats have been fabricated from ethylene--vinyl acetate-millable polyurethane/nanohydroxyapatite (EVA-MPU/nHA) composite systems by employing the electrospinning technique. The ferro-piezoelectric features of the samples were confirmed from the butterfly loops of electrostatic force microscopy (EFM) amplitude signals as well as through the hysteresis curves of the EFM phase recorded with the assistance of dynamic-contact EFM. Piezoelectric responses of the samples to random finger tapping were evaluated after fabricating a simple device prototype connected to an oscilloscope. The efficacy of the mats to generate a voltage in response to activities such as mechanical bending, movement of throat muscles while drinking, movement of elbow joints, air blowing, and so forth has also been investigated. The results suggest the promising possibility of fabricating user-friendly piezoelectric mats out of the EVA-MPU/nHA system for physiological motion-sensing applications.