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碧玉颜色成因及其影响因素。

Genesis and influencing factors of the colour of chrysoprase.

机构信息

School of Gemmology, China University of Geosciences (Beijing), No.29 Xueyuan Road, Beijing, 100083, China.

出版信息

Sci Rep. 2021 May 11;11(1):9939. doi: 10.1038/s41598-021-89406-x.

Abstract

The genesis and influencing factors of the colour of chrysoprase were studied based on the results of transmission electron microscopy and X-ray fluorescence, ultraviolet-visible and Raman spectroscopies. The results show that under a 6504-K fluorescent lamp, chrysoprase colour is divided into the grades of fancy, fancy intense and fancy deep. The lightness of chrysoprase is affected mainly by its chromium content, the chroma is affected by its nickel content and the hue angle is affected by the sum of its chromium and ferrum contents. The colour of chrysoprase is related significantly to the transmission window that occurs between the two main bands centred at 380 and 660 nm and the absorption peaks at 380 and 660 nm in the ultraviolet-visible spectrum. Chrysoprase with low crystallinity has more nickel and a higher chroma. The inclusions that cause the chrysoprase colour have been identified as pimelite.

摘要

基于透射电子显微镜和 X 射线荧光、紫外可见和拉曼光谱的结果,研究了玉髓颜色的成因及其影响因素。结果表明,在 6504K 荧光灯下,玉髓颜色分为 fancy、fancy intense 和 fancy deep 三个等级。玉髓的明度主要受其铬含量的影响,彩度受其镍含量的影响,色调角受其铬和铁含量之和的影响。玉髓的颜色与在紫外可见光谱中位于 380nm 和 660nm 两个主要带之间的传输窗口以及在 380nm 和 660nm 处的吸收峰有关。结晶度低的玉髓含有更多的镍和更高的彩度。导致玉髓颜色的包裹体已被鉴定为磷锰矿。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eda4/8113324/35540105e5b8/41598_2021_89406_Fig1_HTML.jpg

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