(四氢呋喃)Ln(Ge{Si(SiMe)})（Ln = Eu，Sm）：类金属锗簇与镧系元素的首次配位
(thf)Ln(Ge{Si(SiMe)}) (Ln = Eu, Sm): the first coordination of metalloid germanium clusters to lanthanides.
作者信息
Klementyeva Svetlana V, Schrenk Claudio, Zhang Minghui, Khusniyarov Marat M, Schnepf Andreas
机构信息
Chemistry Department, University Tübingen, Auf der Morgenstelle 18, Tübingen 72076, Germany.
Department of Chemistry and Pharmacy Friedrich-Alexander University Erlangen-Nürnberg (FAU) Egerlandstraße 1, Erlangen 91058, Germany.
出版信息
Chem Commun (Camb). 2021 May 11;57(38):4730-4733. doi: 10.1039/d1cc01151k.
We report the synthesis, structure and magnetic properties of the first rare earth complexes of metalloid group 14 clusters [(thf)2Ln(Ge9Hyp3)2] (Ln = Eu, Sm, Hyp = Si(SiMe3)3). X-Ray crystallographic analysis and DFT calculations reveal a novel η2-coordination mode of the Ge9Hyp3 units and a slight distortion of the Ge9 cage.
我们报道了首例类金属14族簇合物[(thf)2Ln(Ge9Hyp3)2]（Ln = Eu、Sm，Hyp = Si(SiMe3)3）的稀土配合物的合成、结构及磁性。X射线晶体学分析和密度泛函理论计算揭示了Ge9Hyp3单元的一种新型η2配位模式以及Ge9笼的轻微畸变。
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