Yan Xin, Liu Guohua, Xu Jinliang, Ma Xiaojing
Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization, North China Electric Power University, Beijing 102206, China.
National Institute of Clean-and-Low-Carbon Energy (NICE), Beijing 102211, China.
Langmuir. 2021 May 25;37(20):6257-6267. doi: 10.1021/acs.langmuir.1c00585. Epub 2021 May 12.
Removal of oil from water is strongly desired due to environmental pollution, and related studies are mainly limited to the material itself. Here, we propose an oil-water separation device, called a floating well, which includes a container for oil collection and a modified mesh screen for oil separation. The mesh screen is superhydrophilic to oil and superhydrophobic to water. The oil removal experiment was performed in a basin. Under the calm surface condition, the oil collection efficiency is shown to be 42-69%. The inadequate oil collection is explained by the breakdown of a thin oil film above water to form an oil-free area, preventing direct contact between the separator and the oil. Sustained by a wave generator, we are surprised to find that with a low-frequency surface wave, the oil collection efficiency is increased to 98%, and the collection speed reaches 2.5 times that under the calm surface condition. The almost complete collection is due to the sustained contact between the separator and the oil, under which the surface wave continuously drives the oil film toward the separator from elsewhere, thus the oil-free area cannot be formed. Our work presents a new clue for large-scale in situ applications, in which the nature wave energy of river/sea can be the driving force for continuous oil separation and collection.
由于环境污染,从水中去除油污的需求十分迫切,相关研究主要局限于材料本身。在此,我们提出一种名为“浮动阱”的油水分离装置,它包括一个用于收集油的容器和一个用于油分离的改性筛网。该筛网对油具有超亲水性,对水具有超疏水性。除油实验在一个水池中进行。在平静水面条件下,集油效率为42%-69%。集油不足的原因是水面上的薄油膜破裂形成无油区,阻止了分离器与油的直接接触。在波浪发生器的作用下,我们惊讶地发现,在低频表面波作用下,集油效率提高到了98%,收集速度达到了平静水面条件下的2.5倍。几乎完全收集是由于分离器与油的持续接触,在此情况下,表面波不断将油膜从其他地方驱向分离器,因此无法形成无油区。我们的工作为大规模原位应用提供了一条新线索,其中河流/海洋的自然波浪能量可成为连续油分离和收集的驱动力。