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芳香族化合物作为海啸回流沉积物替代示踪剂的应用。

An application of aromatic compounds as alternative tracers of tsunami backwash deposits.

作者信息

Pongpiachan Siwatt, Surapipith Vanisa, Hashmi Muhammad Zaffar, Aukkaravittayapun Suparerk, Poshyachinda Saran

机构信息

NIDA Center for Research & Development of Disaster Prevention & Management, School of Social and Environmental Development, National Institute of Development Administration (NIDA), 118 Moo-3, Sereethai Road, Klong-Chan, Bangkapi, Bangkok 10240 Thailand.

SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences (IEECAS), Xi'an, 710075, China.

出版信息

Heliyon. 2021 Apr 24;7(4):e06883. doi: 10.1016/j.heliyon.2021.e06883. eCollection 2021 Apr.

Abstract

This manuscript provides some comprehensive technical insights regarding the application of polycyclic aromatic hydrocarbons (PAHs) characterized by using Gas-Chromatography Mass Spectrometry. Although numerous chemical species such as water soluble ionic species (e.g. Na, K, Cl, Ca, Mg) and acid leachable heavy metal fractions (e.g. Fe, Cd, Al, Mo, Sb, As, Cu, Zn, Pb, and Mn) can be used to characterize tsunami deposits, the knowledge of PAH congeners as alternative chemical species for identifying tsunami backwash deposits is strictly limited. This manuscript is exclusive because it aims to find some alternative chemical proxies in order to distinguish tsunami backwash deposits from typical marine sediments. A wide range of diagnostic binary ratios of PAH congeners have been selected in order to characterize Typical Marine Sediments (TMS), Tsunami backwash deposits (TBD), Onshore Tsunami Deposits (OTD) and Coastal Zone Soils (CZS). The state of the art and future perspectives coupled with both advantages and disadvantages of above mentioned chemical tracers will be critically reviewed and further discussed.

摘要

本手稿提供了一些关于应用气相色谱 - 质谱法表征的多环芳烃(PAHs)的全面技术见解。尽管许多化学物质,如水溶性离子物质(如Na、K、Cl、Ca、Mg)和酸可浸出重金属组分(如Fe、Cd、Al、Mo、Sb、As、Cu、Zn、Pb和Mn)可用于表征海啸沉积物,但作为识别海啸回冲沉积物的替代化学物质,多环芳烃同系物的相关知识却极为有限。本手稿具有独特性,因为其旨在寻找一些替代化学指标,以便将海啸回冲沉积物与典型海洋沉积物区分开来。为了表征典型海洋沉积物(TMS)、海啸回冲沉积物(TBD)、陆上海啸沉积物(OTD)和海岸带土壤(CZS),已选择了多种多环芳烃同系物的诊断二元比。将对上述化学示踪剂的现状和未来前景以及优缺点进行批判性回顾和进一步讨论。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b44/8099755/c8a8d5abb9e9/gr1.jpg

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