Department of Wood and Paper Science and Technology, Natural Resources Faculty, University of Tehran, Iran.
Department of Natural Resources and Earth Science, Shahrekord University, Shahrekord, Iran.
Int J Biol Macromol. 2021 Jul 1;182:1392-1398. doi: 10.1016/j.ijbiomac.2021.05.088. Epub 2021 May 14.
One of the most important environmental issues in the world today is the problem of air pollution, which includes particulate matter (PM) and greenhouse gases (mainly CO). The production of efficient sustainable filters to overcome this concern as well as to provide an alternative to synthetic petroleum-based filters remains a demanding challenge. The purpose of this research was to first produce novel cellulose nanofibers (CNF) based nanofilter from a combination of CNF and chitosan (CS) and then evaluate its applicability for air purification. A number of structural and chemical properties as well as CO and PM adsorption efficiency of the modified CNF, were determined using advanced characterization techniques. After pretests, we determined the optimum loading for the CS was 1 wt%, and upon producing the samples, the CNF loadings (1, 1.5, and 2 wt%) were chosen as one variable. For particle absorption, the PM sizes (0.1, 0.3, 0.5, and 2.5 μm) were kept as other variables. Based on SEM results, we concluded the higher the concentration of CNF the higher the specific surface area and the lower the porosity and the diameter of the pores, which was confirmed by the BET test. Furthermore, the results showed that increasing the concentration of modified CNFs increases the adsorption rate of CO and PM and that the highest adsorption of CO and PM belonged to the 2% modified CNF.
如今,全球最重要的环境问题之一是空气污染问题,其中包括颗粒物 (PM) 和温室气体(主要是 CO)。生产高效可持续的过滤器以解决这个问题,并提供替代合成石油基过滤器的方案仍然是一个具有挑战性的需求。本研究的目的是首先利用纤维素纳米纤维 (CNF) 和壳聚糖 (CS) 的组合来生产新型的基于 CNF 的纳米过滤器,然后评估其在空气净化方面的适用性。使用先进的表征技术确定了改性 CNF 的许多结构和化学性质以及 CO 和 PM 的吸附效率。经过预测试,我们确定 CS 的最佳负载量为 1wt%,然后在制备样品时,选择 CNF 负载量(1、1.5 和 2wt%)作为一个变量。对于颗粒吸收,PM 粒径(0.1、0.3、0.5 和 2.5μm)作为另一个变量。根据 SEM 结果,我们得出结论,CNF 的浓度越高,比表面积越高,孔隙率和孔径越低,这一点通过 BET 测试得到了证实。此外,结果表明,增加改性 CNF 的浓度会提高 CO 和 PM 的吸附速率,而 CO 和 PM 的最高吸附属于 2%改性 CNF。