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阳离子双子表面活性剂对N80碳钢在15%盐酸溶液中溶解速率的抑制作用。

Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution.

作者信息

Deyab M A, Mohsen Q

机构信息

Egyptian Petroleum Research Institute (EPRI), Nasr City, Cairo, Egypt.

Department of Chemistry, College of Sciences, Taif University, Taif, Saudi Arabia.

出版信息

Sci Rep. 2021 May 18;11(1):10521. doi: 10.1038/s41598-021-90031-x.

Abstract

Strong acids are commonly used in petroleum wells to remove scale layers from the surface of N80 C-steel pipe. The corrosive effects of these acids, on the other hand, pose a significant risk to C-steel pipes. For the first time, we discovered the anti-corrosion properties of cationic Gemini surfactant, 1,2-bis(dodecyldimethylammonio) ethane dibromide (DMAEB), for N80 C-steel pipe in acid washing solution (15.0% HCl). The DMAEB, in particular, can reduce the corrosion rate of N80 C-steel by approximately 97%. DMAEB molecules work as a mixed-type corrosion inhibitor, according to electrochemical results. The DMAEB demonstrated a high inhibition effect at high temperatures, as well as high activation energy against the corrosion process. DMAEB's significant performance is primarily due to physical adsorption on the N80 C-steel surface, as confirmed by adsorption isotherms, SEM, EDX, FT-IR, and theoretical studies. Our findings shed new light on the use of Gemini surfactants as corrosion inhibitors in petroleum wells.

摘要

强酸常用于石油井中,以去除N80碳钢管道表面的垢层。另一方面,这些酸的腐蚀性对碳钢管道构成了重大风险。我们首次发现了阳离子双子表面活性剂1,2-双(十二烷基二甲基铵)乙烷二溴化物(DMAEB)在酸洗溶液(15.0%HCl)中对N80碳钢管道的防腐性能。特别是,DMAEB可以将N80碳钢的腐蚀速率降低约97%。电化学结果表明,DMAEB分子作为一种混合型缓蚀剂起作用。DMAEB在高温下表现出高抑制效果,并且对腐蚀过程具有高活化能。吸附等温线、扫描电子显微镜(SEM)、能谱仪(EDX)、傅里叶变换红外光谱(FT-IR)和理论研究证实,DMAEB的显著性能主要归因于其在N80碳钢表面的物理吸附。我们的研究结果为双子表面活性剂在石油井中作为缓蚀剂的应用提供了新的思路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e790/8131745/c2f9b9fc49c3/41598_2021_90031_Fig1_HTML.jpg

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